Characteristics and intermolecular interaction of eutectic binary mixtures: Reline and Glyceline

Farouq Sabri Mjalli; Omar Umar Ahmed

Korean Journal of Chemical Engineering, Vol.33, No.1, 337-343, January, 2016

DOI10.1007/s11814-015-0134-7 Export Citation

Characteristics and intermolecular interaction of eutectic binary mixtures: Reline and Glyceline

Farouq Sabri Mjalli^†, and Omar Umar Ahmed

Petroleum and Chemical Engineering Department, Sultan Qaboos University, Oman

E-mail:

Deep Eutectic Solvents are promising greener and cheaper alternatives to ionic liquids. The applications involving these solvents depend largely on their physical and chemical properties. However, a DES may possess both desirable and undesirable properties for a certain application. In such situations, mixing two DESs, each possessing a unique set of properties, may yield one with a more suitable set of physical and chemical properties for the same application. In this work, the variation in the physical properties of Reline upon addition of Glyceline was investigated. While a positive deviation of excess molar volume was observed, a negative deviation of viscosity was recorded with the increase in Glyceline mol% indicating a disruption of the ordered structure of Reline. The highest deviation in both cases was observed at 30 mol% Glyceline. The physical properties measured were density, viscosity, pH, RI and conductivity. The Glyceline molar percentage studied was 0 to 100mol% while temperature was varied within the range of 20 oC to 80 oC.

Keywords:Mixture;Eutectic;Reline;Glyceline;Molar Volume;Ionic Liquids

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[2] Li C, Li D, Zou S, Li Z, Yin J, Wang A, Cui Y, Yao Z, Zhao Q, Green Chem., 15, 2793 (2013)

[3] Abbott AP, Capper G, McKenzie KJ, Ryder KS, Electrochim. Acta, 51, 4420 (2006)

[4] Morrison HG, Sun CC, Neervannan S, Int. J. Pharm., 378, 136 (2009)

[5] Abbott AP, Barron JC, Ryder KS, Wilson D, Chem.-Eur. J., 13, 6495 (2007)

[6] Zhao H, Baker GA, Holmes S, J. Mol. Catal. B-Enzym., 72, 163 (2011)

[7] Gorke JT, Srienc F, Kazlauskas RJ, Chem. Commun., 1235 (2008)

[8] Zhang Q, De Oliveira Vigier K, Royer S, Jerome F, Chem. Soc. Rev., 41, 7108 (2012)

[9] Rimsza JM, Corrales LR, Comput. Theor. Chem., 987, 57 (2012)

[10] Phadtare SB, Shankarling GS, Green Chem., 12, 458 (2010)

[11] Liao JH, Wu PC, Bai YH, Inorg. Chem. Commun., 8, 390 (2005)

[12] Annat G, Forsyth M, MacFarlane DR, J. Phys. Chem. B, 116(28), 8251 (2012)

[13] Chatel G, Pereira JFB, Debbeti V, Wang H, Rogers RD, Green Chem., 16, 2051 (2014)

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[15] Gonzalez EJ, Dominguez A, Macedo EA, J. Chem. Thermodyn., 47, 300 (2012)

[16] Kohno Y, Ohno H, Chem. Commun., 48, 7119 (2012)

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[18] Leron RB, Soriano AN, Li MH, J. Taiwan Inst. Chem. Eng., 43, 551 (2012)

[19] Shah D, Mjalli FS, Phys. Chem. Chem. Phys., 16, 23900 (2014)

[20] Wu SH, Caparanga AR, Leron RB, Li MH, Thermochim. Acta, 544, 1 (2012)

[21] Harris RC, University of Leicester, Leicester (2008).

[22] Dougherty RC, J. Chem. Phys., 109(17), 7372 (1998)

[23] Mahajan AR, Mirgane SR, J. Thermodyn., 2013, 11 (2013)

[24] Iloukhani H, Rezaei-Sameti M, Basiri-Parsa J, J. Chem. Thermodyn., 38(8), 975 (2006)

[25] Fort RJ, Moore WR, J. Chem. Soc.-Faraday Trans., 62, 1112 (1966)

[26] Liu YG, Daum PH, J. Aerosol Sci., 39(11), 974 (2008)