화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.31, 156-166, November, 2015
DOI10.1016/j.jiec.2015.06.019  Export Citation
Synthesis of copper-nickel/SBA-15 from rice husk ash catalyst for dimethyl carbonate production from methanol and carbon dioxide
Siraprapa Pimprom1, Khemmachat Sriboonkham1, Peerapan Dittanet1, Karin Fottinger2, Gunther Rupprechter2, and Paisan Kongkachuichay1, 3, †
  • 1Department of Chemical Engineering, Faculty of Engineering, Kasetsart University, Bangkok 10900, Thailand
  • 2Institute of Materials Chemistry/Physical Chemistry Division, Vienna University of Technology, Getreidemarkt 9, A-1060 Vienna, Austria
  • 3Center for Advanced Studies in Nanotechnology and Its Applications in Chemical, Food and Agricultural Industries, Kasetsart University, Bangkok 10900, Thailand
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The SBA-15 was synthesized via sol.gel process by using rice hush ash and tetraethyl orthosilicate as silica sources at a ratio of 50:50. Subsequently, Cu.Ni bimetals were loaded on the SBA-15 and were tested for the direct synthesis of dimethyl carbonate from CH3OH and CO2. FTIR showed that methanol reacted with pre-adsorbed carbon dioxide to form methoxy carbonate species that was the reaction intermediate. It was found that 0.5 g of catalyst with Cu and Ni bimetal loading of 5 wt% exhibited the highest activities. Moreover, the molybdenum modified catalyst showed greater beneficial effects on the stabilization of the catalyst.
Keywords:Dimethyl carbonate;Methanol;Carbon dioxide;Mesoporous silica;SBA-15
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