Fabrication of polyvinylchloride based nanocomposite thin film filled with zinc oxide nanoparticles: Morphological, thermal and optical characteristics

M. Zarrinkhameh; A. Zendehnam; S.M. Hosseini

Journal of Industrial and Engineering Chemistry, Vol.30, 295-301, October, 2015

DOI10.1016/j.jiec.2015.05.036 Export Citation

Fabrication of polyvinylchloride based nanocomposite thin film filled with zinc oxide nanoparticles: Morphological, thermal and optical characteristics

M. Zarrinkhameh, A. Zendehnam, and S.M. Hosseini^{1, †}

Thin film laboratory, Department of physic, Faculty of Science, Arak University, Arak 38156-8-8349, Iran
¹Department of Chemical Engineering, Faculty of Engineering, Arak University, Arak 38156-8-8349, Iran

E-mail:

PVC-co-ZnO nanocomposite film was prepared by solution casting technique with different concentration of zinc oxide nanoparticle. Optical measurements showed that utilizing zinc oxide nanoparticle in polymeric matrix caused to increase of UV absorption obviously. X-ray diffraction showed polycrystalline structure with no preferred orientation for prepared nanocomposite films. Atomic force microscopy images also showed smooth surfaces for the nanocomposite films. The thermal properties investigation of prepared films revealed that utilizing ZnO nanoparticles in polymeric matrix accelerated the polymer decomposition which was assigned to catalytic behavior of zinc oxide nanoparticles. Moreover, utilizing zinc oxide nanoparticles enhanced the char yield of prepared films.

Keywords:Nanocomposite;PVC based film;Zinc oxide nanoparticles;Fabrication;Morphological/Thermal/Optical;characteristic

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[2] Hayashi S, Fujiki K, Tsubokawa N, React. Funct. Polym., 46(2), 193 (2000)

[3] Fleming MS, Mandal TK, Walt DR, Chem. Mater., 13, 2210 (2001)

[4] Chen J, Cheng CY, Chiu WY, Lee CF, Liang NY, Eur. Polym. J., 44, 3271 (2008)

[5] Huang MH, Mao S, Feick H, Yan H, Wu Y, Kind H, Science, 292, 1897 (2001)

[6] Krishnamoorthy S, Iliadis AA, Solid-State Electron., 52(11), 1710 (2008)

[7] Yamamoto N, Makino H, Osone S, Ujihara A, Ito T, Hokari H, Maruyama T, Yamamoto T, Thin Solid Films, 520(12), 4131 (2012)

[8] Li Q, Mahendra S, Delina YL, Brunet L, Michael VL, Li D, Pedro JJA, Water. Res., 42, 4591 (2008)

[9] Pauporte T, Rathousky J, J. Phys. Chem. C, 111, 7639 (2007)

[10] NairManjula G, Nirmala M, Rekha K, Anukalian A, Mater. Lett., 65, 1797 (2011)

[11] Xiong H, Liu D, Xia Y, Chen J, Chem. Mater., 17, 3062 (2005)

[12] Tang EJ, Cheng GX, Pang XS, Colloid Polym. Sci., 284, 422 (2006)

[13] El-Hady MMA, Farouk A, Sharaf S, Carbohydr. Polym., 92, 400 (2013)

[14] Li RX, Yabe S, Yamashita M, Momose S, Yoshida S, Yin S, Sato T, Solid State Ion., 151(1-4), 235 (2002)

[15] Lamba N, Courtney J, Biomaterials, 21, 89 (2000)

[16] Starnes WH, Prog. Polym. Sci, 27, 2133 (2002)

[17] Basfar AA, Polym. Degrad. Stabil., 82, 333 (2003)

[18] Sawai J, J. Microbiol. Meth., 54, 177 (2003)

[19] Cho SW, Jeong JA, Bae JH, Moon JM, Choi KH, Jeong SW, Park NJ, Kim JJ, Lee SH, Kang JW, Yi MS, Kim HK, Thin Solid Films, 516(21), 7881 (2008)

[20] Zarrinkhameh M, Zendehnam A, Hosseini SM, J. Polym. Res., 20, 283 (2013)

[21] Zendehnam A, Robatmili N, Hosseini SM, Arabzadegan M, Madaeni SS, J. Taiwan Inst. Chem. Eng., 44, 670 (2013)

[22] Khan MMA, Rafiuddin I, J. Ind. Eng. Chem., 19, 136513 (2013)

[23] Hosseini SM, Madaeni SS, Zendehnam A, Moghadassi AR, Khodabakhshi AR, Sanaeepur H, J. Ind. Eng. Chem., 19(3), 854 (2013)

[24] Hosseini SM, Askari M, Koranian P, Madaeni SS, Moghadassi AR, J. Ind. Eng. Chem., 20(4), 2510 (2014)

[25] Dutta S, Chattopadhyay S, Sarkar A, Chakrabarti M, Sanyal D, Jana D, Prog. Mater. Sci., 54(1), 89 (2009)

[26] Xiong G, Ucer KB, Williams RT, Lee J, Bhattacharyya D, Metson J, Evans P, J. Appl. Phys., 97, 043528 (2005)

[27] Yang HY, Yu SF, Li GP, Wu T, Optics Express, 18, 13647 (2010)

[28] Erertovr L, Physics of Thin Films, Second edition, Plenum press, New York, USA, 1986.

[29] Tang EJ, Fu CY, Wang S, Dong SY, Zhao FQ, Zhao DS, Powder Technol., 218, 5 (2012)

[30] Mensker KC, Fedoseeva GT (Eds.), The Degradation and Stabilization of PVC, Chemistry Press, USSR, 1979.

[31] Gong F, Feng M, Zhao C, Zhang S, Yang M, Polym. Degrad. Stabil., 84, 289 (2004)

[32] Hung YJ, Ng KL, Huang HY, Int. J. Hydrog. Energy, 36, 5203 (2011)

[33] McCrum NG, Buckley GP, Bucknall CB, Definition taken from Principles of Polymer Engineering (2nd edition).