Adsorption of hexavalent chromium by metal organic frameworks from aqueous solution

Afshin Maleki; Bagher Hayati; Maryam Naghizadeh; Sang W. Joo

Journal of Industrial and Engineering Chemistry, Vol.28, 211-216, August, 2015

DOI10.1016/j.jiec.2015.02.016 Export Citation

Adsorption of hexavalent chromium by metal organic frameworks from aqueous solution

Afshin Maleki, Bagher Hayati, Maryam Naghizadeh, and Sang W. Joo^{1, †}

Kurdistan Environmental Health Research Center, Kurdistan University of Medical Sciences, Sanandaj, Iran
¹School of Mechanical Engineering, Yeungnam University, Gyeongsan 712-749, Republic of Korea

E-mail:

A metal-organic frameworks (MOFs) based on copper-benzenetricarboxylates is applied to the adsorption of hexavalent chromium from aqueous solution. Characterization of Cu-BTC was achieved by XRD, SEM micrographs, nitrogen adsorption.desorption analysis and FT-IR spectra. The kinetic characteristics and thermodynamic parameters are also analyzed. The experimental isotherm data are analyzed using Langmuir and Freundlich isotherm equations. Thermodynamic parameters are calculated by the Gibbs free energy function, confirming that the adsorption process was spontaneous and accompanied by exothermic. The maximum removal has been achieved at pH = 7.0. Possible mechanism and adsorption behavior of hexavalent chromium onto Cu-BTC are investigated.

Keywords:Metal organic frameworks;Adsorption;Chromium wastewater;Kinetic model;Langmuir isotherm

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[Referenced By]

[1] Rao A, Bankar A, Kumar AR, Gosavi S, Zinjarde S, J. Contam. Hydrol., 146, 63 (2013)

[2] Sidiras D, Politi D, Batzias F, Boukos N, Int. J. Environ. Sci. Technol., 10, 1337 (2013)

[3] Yokoyama S, Okazaki K, Sasano J, Izaki M, The IRAGO Conference 2013, AIP Publishing, 2014, pp. 181-189.

[4] Khedr S, Shouman M, Fathy N, Attia A, ISRN Environ. Chem., 76, 398 (2014)

[5] Chen J, Hong X, Zhao Y, Zhang Q, Water Sci. Technol., 70, 678 (2014)

[6] Khosravi R, Fazlzadehdavil M, Barikbin B, Taghizadeh AA, Appl. Surf. Sci., 292, 670 (2014)

[7] Teng HH, Xu SK, Zhao CY, Lv FT, Liu HB, Sep. Sci. Technol., 48(11), 1729 (2013)

[8] Liu K, Liu JY, Xie YB, Deng JQ, Huang GH, Plat. Finish., 3, 015 (2013)

[9] Sun YY, Yue QY, Gao BY, Gao Y, Li Q, Wang Y, Chem. Eng. J., 217, 240 (2013)

[10] Kumar KS, Roy S, Development, 25, 27 (2013)

[11] Deveci H, Kar Y, J. Ind. Eng. Chem., 19(1), 190 (2013)

[12] Kundu A, Redzwan G, Sahu JN, Mukherjee S, Gupta BS, Hashim MA, Bioresour. Technol., 9, 1498 (2014)

[13] Khan NA, Hasan Z, Jhung SH, J. Hazard. Mater., 244, 444 (2013)

[14] Liu T, Che JX, Hu YZ, Dong XY, Liu CM, Chem. Eur. J., 20, 1409 (2014)

[15] Gaur J, Jain S, Bhatia R, Lal A, Kaushik NK, J. Therm. Anal. Calorim., 112, 1137 (2013)

[16] Haque E, Jun JW, Jhung SH, J. Hazard. Mater., 185, 507 (2011)

[17] Huang XX, Qiu LG, Zhang W, Yuan YP, Jiang X, Xie AJ, Shen YH, Zhu JF, CrystEngComm, 14, 1613 (2012)

[18] Carboni M, Abney CW, Liu S, Lin W, Chem. Sci., 4, 2396 (2013)

[19] Li H, Eddaoudi M, O’Keeffe M, Yaghi OM, Nature, 402, 276 (1999)

[20] Duren T, Bae YS, Snurr RQ, Chem. Soc. Rev., 38, 1237 (2009)

[21] Osta RE, Feyand M, Stock N, Millange F, Walton RI, Powder Diffr., 28, S256 (2013)

[22] Puskaric A, Halasz I, Kontrec J, Bronic J, Fifth Serbian-Croatian-Slovenian Symposium on Zeolites, 2013.

[23] Yue Y, Binder AJ, Song R, Cui Y, Chen J, Hensley DK, Dai S, J. Chem. Soc.-Dalton Trans., 35, 107 (2014)

[24] Fracaroli AM, Furukawa H, Suzuki M, Dodd M, Okajima S, Gandara F, Reimer JA, Yaghi OM, J. Am. Chem. Soc., 136(25), 8863 (2014)

[25] Brozek CK, Dinca M, J. Am. Chem. Soc., 135(34), 12886 (2013)

[26] Zhang NT, Yang X, Yu XY, Jia Y, Wang J, Kong LT, Jin Z, Sun B, Luo T, Liu JH, Chem. Eng. J., 252, 220 (2014)

[27] Li XJ, Zheng LY, Huang LZ, Zheng O, Lin ZY, Guo LH, Qiu B, Chen GN, J. Appl. Polym. Sci., 129(5), 2857 (2013)

[28] Ng C, Losso JN, Marshall WE, Rao RM, Bioresour. Technol., 85(2), 131 (2002)

[29] Mcrae RL, Phillips RL, Kim IB, Bunz UHF, Fahrni CJ, J. Am. Chem. Soc., 130(25), 7851 (2008)

[30] Das SK, Bhowal J, Das AR, Guha AK, Langmuir, 22(17), 7265 (2006)

[31] Choy KKH, Porter JF, Mckay G, Chem. Eng. J., 103(1-3), 133 (2004)

[32] Cai QY, Mo CH, Wu QT, Zeng QY, Katsoyiannis A, Ferard JF, J. Hazard. Mater., 142(1-2), 535 (2007)

[33] Mahmoodi NM, J. Chem. Eng. Data, 56(6), 2802 (2011)

[34] Mahmoodi NM, Hayati B, Bahrami H, Arami M, J. Appl. Polym. Sci., 122(3), 1489 (2011)

[35] Woodard IC, Industrial Waste Treatment Handbook, Butterworth-Heinemann, Burlington, Massachusetts, USA, 2006.

[36] Alley ER, Water Quality Control Handbook, McGraw-Hill, New York, USA, 2007.

[37] Quintelas C, Sousa E, Silva F, Neto S, Tavares T, Process Biochem., 41, 2087 (2006)

[38] Ho Y, Chiang C, Adsorption, 7, 139 (2001)

[39] Shan HY, Scientometrics, 59, 171 (2004)

[40] Ho YS, McKay G, Water Res., 34, 735 (2000)

[41] Gercel O, Ozcan A, Ozcan AS, Gercel HF, Appl. Surf. Sci., 253(11), 4843 (2007)