화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.28, 138-146, August, 2015
DOI10.1016/j.jiec.2015.02.009  Export Citation
Catalytic decomposition of N2O over RhOx supported on metal phosphates
Yi Lin, Tao Meng, and Zhen Ma†
  • Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention (LAP3), Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, China
E-mail:
RhOx/M-P-O (M = Mg, Al, Ca, Fe, Co, Zn, La) catalysts were tested in N2O decomposition. RhOx/Ca-P-O showed the highest activity, achieving complete N2O conversion at 300 8C. RhOx/La-P-O is the second most active catalyst, achieving almost complete conversion at 375 8C. RhOx/Mg-P-O, RhOx/Co-P-O, and RhOx/Al-P-O showed lower activities, whereas RhOx/Fe-P-O and RhOx/Zn-P-O were completely inactive. The high activity of RhOx/Ca-P-O is ascribed to the presence of very small RhOx particles, more basic sites, and the easiness of desorbing O2 at low temperatures. The inhibiting effects of co-fed O2 and/ or H2O on the catalytic activity of RhOx/Ca-P-O are reversible.
Keywords:N2O decomposition;Rhodium catalyst;Hydroxyapatite;Metal phosphate
  1. Takita Y, Sano K, Kurosaki K, Kawata N, Nishiguchi H, Ito M, Ishihara T, Appl. Catal. A: Gen., 167(1), 49 (1998)
  2. Takita Y, Ninomiya M, Matsuzaki R, Wakamatsu H, Nishiguchi H, Ishihara T, Phys. Chem. Chem. Phys., 1, 2367 (1999)
  3. Takita Y, Wakamatsu H, Tokumaru M, Nishiguchi H, Ito M, Ishihara T, Appl. Catal. A: Gen., 194-195, 55 (2000)
  4. Kashiwagi D, Takai A, Takubo T, Nagaoka K, Inoue T, Takita Y, Ind. Eng. Chem. Res., 48, 632 (2008)
  5. Kashiwagi D, Takai A, Takubo T, Yamada H, Inoue T, Nagaoka K, Takita Y, J. Colloid Interface Sci., 332(1), 136 (2009)
  6. Takubo T, Hirose Y, Kashiwagi D, Inoue T, Yamada H, Nagaoka K, Takita Y, Catal. Commun., 11, 147 (2009)
  7. Ren T, Yan L, Zhang XM, Suo JS, Appl. Surf. Sci., 244, 11 (2003)
  8. Yan WF, Brown S, Pan ZW, Mahurin SM, Overbury SH, Dai S, Angew. Chem.-Int. Edit., 45, 3614 (2006)
  9. Ma Z, Brown S, Overbury SH, Dai S, Appl. Catal. A: Gen., 327(2), 226 (2007)
  10. Ma Z, Yin HF, Overbury SH, Dai S, Catal. Lett., 126(1-2), 20 (2008)
  11. Li MJ, Wu ZL, Overbury SH, J. Catal., 278(1), 133 (2011)
  12. Wang Y, Yuan Q, Zhang QH, Deng WP, J. Phys. Chem., 111, 2044 (2007)
  13. Takita Y, Ohkuma T, Nishiguchi H, Nagaoka K, Nakajo T, Appl. Catal. A: Gen., 283(1-2), 47 (2005)
  14. Hernandez-Huesca R, Merida-Robles J, Maireles-Torres P, Rodriguez-Castellon E, Jimenez-Lopez A, J. Catal., 203(1), 122 (2001)
  15. Pelletier L, Liu DDS, Appl. Catal. A: Gen., 317(2), 293 (2007)
  16. Yuan Q, Zhang QH, Wang Y, J. Catal., 233(1), 221 (2005)
  17. Sebti S, Tahir R, Nazih R, Saber A, Boulaajaj S, Appl. Catal. A: Gen., 228(1-2), 155 (2002)
  18. Gruselle M, Kanger T, Thouvenot R, Flambard A, Kriis K, Mikli V, Traksmaa R, Maaten B, Tonsuaadu K, ACS Catal., 1, 1729 (2011)
  19. Sugiyama S, Minami T, Hayashi H, Tanaka M, Moffat JB, J. Solid State Chem., 126, 242 (1996)
  20. Tsuchida T, Kubo J, Yoshioka T, Sakuma S, Takeguchi T, Ueda W, J. Catal., 259(2), 183 (2008)
  21. Xu J, White T, Li P, He CH, Han YF, J. Am. Chem. Soc., 132(38), 13172 (2010)
  22. Huang J, Wang LC, Liu YM, Cao Y, He HY, Fan KN, Appl. Catal. B: Environ., 101(3-4), 560 (2011)
  23. Wang JD, Liu JK, Lu Y, Hong DJ, Yang XH, Mater. Res. Bull., 55, 190 (2014)
  24. Jaworski JW, Cho S, Kim Y, Jung JH, Jeon HS, Min BK, Kwon KY, J. Colloid Interface Sci., 394, 401 (2013)
  25. Huang L, Luo PF, Pei WG, Liu XY, Wang Y, Wang J, Xing WH, Huang J, Adv. Synth. Catal., 354, 2689 (2012)
  26. Celik D, Karahan S, Zzhmakiran M, Ozkar S, Int. J. Hydrog. Energy, 37(6), 5143 (2012)
  27. Parres-Esclapez S, Such-Basanez I, Illan-Gomez MJ, de Lecea CSM, Bueno-Lopez A, J. Catal., 276(2), 390 (2010)
  28. Bueno-Lopez A, Such-Basanez I, de Lecea CSM, J. Catal., 244(1), 102 (2006)
  29. Imanaka N, Masui T, Appl. Catal. A: Gen., 431, 1 (2012)
  30. Dandekar A, Vannice MA, Appl. Catal. B: Environ., 22(3), 179 (1999)
  31. Kondratenko VA, Baerns M, J. Catal., 225(1), 37 (2004)
  32. Satsuma A, Maeshima H, Watanabe K, Suzuki K, Hattori T, Catal. Today, 63(2-4), 347 (2000)
  33. Karlsen EJ, Nygren MA, Pettersson LGM, J. Phys. Chem. A, 106(34), 7868 (2002)
  34. Kapteijn F, Rodriguezmirasol J, Moulijn JA, Appl. Catal. B: Environ., 9(1-4), 25 (1996)
  35. Zou W, Xie PF, Hua WM, Wang YD, Kong DJ, Yue YH, Ma Z, Yang WM, Gao Z, J. Mol. Catal. A-Chem., 394, 83 (2014)
  36. Xie PF, Ma Z, Zhou HB, Huang CY, Yue YH, Shen W, Xu HL, Hua WM, Gao Z, Microporous Mesoporous Mater., 194, 112 (2014)
  37. Rutkowska M, Chmielarz L, Macina D, Piwowarska Z, Dudek B, Adamski A, Witkowski S, Sojka Z, Obalova L, Van Oers CJ, Cool P, Appl. Catal. B: Environ., 146, 112 (2014)
  38. Centi G, Dall'Olio L, Perathoner S, J. Catal., 194(1), 130 (2000)
  39. Rico-Perez V, de Lecea CSM, Bueno-Lopez A, Appl. Catal. A: Gen., 472, 134 (2014)
  40. Kim SS, Lee SJ, Hong SC, J. Ind. Eng. Chem., 18(4), 1263 (2012)
  41. Parres-Esclapez S, Illan-Gomez MJ, de Lecea CSM, Bueno-Lopez A, Appl. Catal. B: Environ., 96(3-4), 370 (2010)
  42. Zhao XY, Cong Y, Huang YQ, Liu SA, Wang XD, Zhang T, Catal. Lett., 141(1), 128 (2011)
  43. Reddy PSS, Babu NS, Pasha N, Lingaiah N, Prasad PSS, Catal. Commun., 9, 2303 (2008)
  44. Yuzaki K, Yarimizu T, Aoyagi K, Ito S, Kunimori K, Catal. Today, 45(1-4), 129 (1998)
  45. Yuzaki K, Yarimizu T, Ito S, Kunimori K, Catal. Lett., 47(3-4), 173 (1997)
  46. Suarez S, Yates M, Petre AL, Martin JA, Avila P, Blanco J, Appl. Catal. B: Environ., 64(3-4), 302 (2006)
  47. Hussain M, Fino D, Russo N, J. Hazard. Mater., 211-212, 255 (2012)
  48. Hussain M, Fino D, Russo N, Chem. Eng. J., 238, 198 (2014)
  49. Beyer H, Emmerich J, Chatziapostolou K, Koohler K, Appl. Catal. A: Gen., 391(1-2), 411 (2011)
  50. Chmielarz L, Kus´trowski P, Drozdek M, Rutkowska M, Dziembaj R, Michalik M, Cool P, Vansant E, J. Porous Mat., 18, 483 (2011)
  51. Xu XD, Xu HL, Kapteijn F, Moulijn JA, Appl. Catal. B: Environ., 53(4), 265 (2004)
  52. Ma Z, Overbury SH, Dai S, J. Mol. Catal. A-Chem., 273(1-2), 186 (2007)
  53. Soria J, Martinez-Arias A, Fierro JLG, Conesa JC, Vacuum, 46, 1201 (1995)
  54. Oi J, Obuchi A, Bamwenda GR, Ogata A, Yagita H, Kushiyama S, Mizuno K, Appl. Catal. B: Environ., 12(4), 277 (1997)
  55. Brow RK, J. Non-Cryst. Solids, 194, 267 (1996)
  56. Grosseau-Poussard JL, Panicaud B, Pedraza F, Renault PO, Silvain JF, J. Appl. Phys., 94, 784 (2003)
  57. Haque P, Ahmed I, Parsons A, Felfel R, Walker G, Rudd C, J. Non-Cryst. Solids, 375, 99 (2013)
  58. Herzing AA, Kiely CJ, Carley AF, Landon P, Hutchings GJ, Science, 321, 1331 (2008)
  59. Gougousi T, Chen ZY, Thin Solid Films, 516(18), 6197 (2008)
  60. Chen GX, Zhao Y, Fu G, Duchesne PN, Gu L, Zheng YP, Weng XF, Chen MS, Zhang P, Pao CW, Lee JF, Zheng NF, Science, 344(6183), 495 (2014)
  61. Muresan LE, Oprea BF, Cadis AI, Perhaita I, Ponta O, J. Alloy. Compd., 615, 795 (2014)
  62. Watson KE, Tenhuisen KS, Brown PW, J. Mater. Sci. -Mater. Med., 10, 205 (1999)
  63. Diaz-Guillen JA, Fuentes AF, Gallini S, Colomer MT, J. Alloy. Compd., 427, 87 (2007)
  64. Hachani S, Moine B, El-akrmi A, Ferid M, Opt. Mater., 31, 678 (2009)
  65. Zaghib K, Julien CM, J. Power Sources, 142(1-2), 279 (2005)
  66. Yang H, Zhang L, Xu KW, Appl. Surf. Sci., 254(2), 425 (2007)
  67. Haber J, Machej T, Janas J, Nattich M, Catal. Today, 90(1-2), 15 (2004)
  68. Haber J, Nattich M, Machej T, Appl. Catal. B: Environ., 77(3-4), 278 (2008)
  69. Xue L, He H, Liu C, Zhang CB, Zhang B, Environ. Sci. Technol., 43, 890 (2009)
  70. Naresh D, Kumar VP, Harisekhar M, Nagaraju N, Putrakumar B, Chary KVR, Appl. Surf. Sci., 314, 199 (2014)
  71. Diallo-Garcia S, Ben Osman M, Krafft JM, Boujday S, Guylene C, Catal. Today, 226, 81 (2014)
  72. Diallo-Garcia S, Osman MB, Krafft JM, Casale S, Thomas C, Kubo J, Costentin G, J. Phys. Chem., 118, 12744 (2014)
  73. Ohnishi C, Asano K, Iwamoto S, Chikama K, Inoue M, Catal. Today, 120(2), 145 (2007)
  74. Kondratenko EV, Perez-Ramirez J, Catal. Lett., 91(3-4), 211 (2003)
  75. Centi G, Perathoner S, Vazzana F, Marella M, Tomaselli M, Mantegazza M, Adv. Environ. Res., 4, 325 (2000)
  76. Huang CY, Ma Z, Xie PF, Yue YH, Hua WM, Gao Z, J. Mol. Catal. A-Chem., 400, 90 (2015)