화학공학소재연구정보센터
Korean Chemical Engineering Research, Vol.53, No.5, 576-583, October, 2015
Cempedak Durian (Artocarpus sp.) Peel as a Biosorbent for the Removal of Toxic Methyl Violet 2B from Aqueous Solution
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This paper aims to investigate the potential use of cempedak durian peel (CDP) from Negara Brunei Darussalam, which is low-cost, locally available, eco-friendly and highly efficient to remove methyl violet (MV) dye from aqueous solutions. The time required for equilibrium to be reached is 2.0 h with no adjustment of pH necessary. FTIR analysis was indicative of the involvement of -COOH and C=O functional groups in adsorption process. The Langmuir model provided the best fit with maximum adsorption capacity of 0.606 mmol g-1. Thermodynamics data indicate that the adsorption is spontaneous, feasible and endothermic in nature. Best regeneration of CDP’s adsorption ability is achieved by base solution, showing about 95% removal efficiency of MV even after 5 cycles, indicating that CDP can be regenerated and reused. This, together with its high adsorption capacity, makes CDP a potential adsorbent for the removal of MV in wastewater.
  1. Aksu Z, Process Biochem., 40, 997 (2005)
  2. Rahchamani J, Mousavi HZ, Behzad M, Desalination, 267(2-3), 256 (2011)
  3. Rajeshwarisivaraj, Sivakumar S, Senthilkumar P, Subburam V, Bioresour. Technol., 80(3), 233 (2001)
  4. Abdolali A, Guo WS, Ngo HH, Chen SS, Nguyen NC, Tung KL, Bioresour. Technol., 160, 57 (2014)
  5. Deniz F, Karaman S, Saygideger SD, Desalination, 270(1-3), 199 (2011)
  6. Dahri MK, Kooh MRR, Lim LBL, ISRN Environ. Chem., 2013 (2013)
  7. Chieng HI, Lim LBL, Priyantha N, J. Appl. Sci. Environ. Sanitat., 8, 303 (2013)
  8. Chieng HI, Zehra T, Lim LBL, Priyantha N, Tennakoon DTB, Environ. Earth. Sci., 72, 2263 (2014)
  9. Zehra T, Priyantha N, Lim LBL, Iqbal E, Desalin. Water Treat., 1 (2014)
  10. Chieng HI, Lim LBL, Priyantha N, Desalin. Water Treat., 1 (2014)
  11. Wu YH, Jiang L, Mi XM, Li B, Feng SX, Korean J. Chem. Eng., 28(3), 895 (2011)
  12. Rehman MSU, Munir M, Ashfaq M, Rashid N, Nazar MF, Danish M, Han JI, Chem. Eng. J., 228, 54 (2013)
  13. Lim LBL, Priyantha N, Chan CM, Matassan D, Chieng HI, Kooh MRR, Arab. J. Sci. Eng., 39, 6757 (2014)
  14. Rajaram R, Banu JS, Mathivanan K, Toxicol. Environ. Chem., 95, 590 (2013)
  15. Mao J, Won SW, Min J, Yun YS, Korean J. Chem. Eng., 25(5), 1060 (2008)
  16. Priyantha N, Lim LBL, Dahri MK, Tennakoon DTB, J. Appl. Sci. Environ. Sanitat., 8, 179 (2013)
  17. Bhatti HN, Bajwa II, Hanif MA, Bukhari IH, Korean J. Chem. Eng., 27(1), 218 (2010)
  18. Lim LBL, Priyantha N, Ramli UK, Chieng HI, J. Appl. Phytotechnol. Environ. Sanitat., 3, 65 (2014)
  19. Lafi R, Fradj A, Hafiane A, Hameed BH, Korean J. Chem. Eng., 31(12), 2198 (2014)
  20. Keshtkar AR, Hassani MA, Korean J. Chem. Eng., 31(2), 289 (2014)
  21. Lee HS, Suh JH, Korean J. Chem. Eng., 17(4), 477 (2000)
  22. Lillie RD, Conn HJ, Conn’s Biological Stains: a Handbook on the Nature and Uses of the Dyes Employed in the Biological Laboratory, Williams & Wilkins, Baltimore(1977).
  23. Hameed BH, J. Hazard. Mater., 154(1-3), 204 (2008)
  24. Slokar YM, Majcen L, Marechal A, Dyes Pigment., 37, 335 (1998)
  25. Vachalkova A, Novotny L, Blesova M, Neoplasma, 43, 113 (1996)
  26. Tang YP, Lim LBL, Wimmer FL, Int. Food. Res. J., 20, 409 (2013)
  27. Lim LBL, Chieng HI, Wimmer FL, ASEAN J. Sci. Technol. Dev., 28, 122 (2011)
  28. Lim LBL, Priyantha N, Ing CH, Dahri MK, Tennakoon DTB, Zehra T, Suklueng M, Desalin. Water Treat., 1 (2013)
  29. Chieng HI, Lim LBL, Priyantha N, Environ. Technol., 36, 86 (2014)
  30. Lim LBL, Priyantha N, Tennakoon DTB, Dahri MK, Envion. Sci. Pollut. Res., 19, 3250 (2012)
  31. Shawabkeh R, Al-Khashman O, Al-Omari H, Shawabkeh A, Environmentalist, 27, 357 (2007)
  32. Ghaedi M, Hossainian H, Montazerozohori M, Shokrollahi A, Shojaipour F, Soylak M, Purkait MK, Desalination, 281, 226 (2011)
  33. Langmuir I, J. Am. Chem. Soc., 40, 1361 (1918)
  34. Freundlich HMF, J. Phys. Chem., 57, 385 (1906)
  35. Redlich O, Peterson DL, J. Phys. Chem., 63, 1024 (1959)
  36. Tsai SC, Juang KW, J. Radioanal. Nucl. Chem., 243, 741 (2000)
  37. Weber TW, Chakravorti RK, J. Amer. Inst. Chem. Engrs., 20, 228 (1974)
  38. McKay G, Blair HS, Gardner JR, J. Appl. Polym. Sci., 27, 3043 (1982)
  39. Annadurai G, Juang RS, Lee DJ, J. Hazard. Mater., 92(3), 263 (2002)
  40. Li P, Su YJ, Wang Y, Liu B, Sun LM, J. Hazard. Mater., 179(1-3), 43 (2010)
  41. Cengiz S, Cavas L, Mar. Biotechnol., 6, 728 (2010)
  42. Duran C, Ozdes D, Gundogdu A, Senturk HB, J. Chem. Eng. Data, 56(5), 2136 (2011)
  43. Mane VS, Babu PVV, Desalination, 273(2-3), 321 (2011)
  44. Lagergren S, K. Sven. Vetenskapsakad. Handl., 24, 1 (1898)
  45. Ho YS, McKay G, Process Biochem., 34(5), 451 (1999)
  46. Weber W, Morris J, J. Sanit. Eng. Div., 89, 31 (1963)
  47. Boyd GE, Adamson AW, Myers LS, J. Am. Chem. Soc., 69, 2836 (1947)
  48. Li Q, Yue QY, Su Y, Gao BY, Fu L, J. Hazard. Mater., 147(1-2), 370 (2007)
  49. Akkaya G, Ozer A, Process Biochem., 40, 3559 (2005)
  50. Gad HMH, El-Sayed AA, J. Hazard. Mater., 168(2-3), 1070 (2009)
  51. Hu YQ, Guo T, Ye XS, Li Q, Guo M, Liu HN, Wu ZJ, Chem. Eng. J., 228, 392 (2013)
  52. Vilar VJP, Botelho CMS, Boaventura RAR, Process Biochem., 40, 3267 (2005)
  53. Newcombe G, Drikas M, Carbon, 35, 1239 (1997)
  54. Abdallah R, Taha S, Chem. Eng. J., 195, 69 (2012)
  55. Kumar D, Gaur JP, Bioresour. Technol., 102(3), 2529 (2011)
  56. Fernandez ME, Nunell GV, Bonelli PR, Cukierman AL, Bioresour. Technol., 106, 55 (2012)
  57. Chowdhury S, Misra R, Kushwaha P, Das P, Biorem. J., 15, 77 (2011)