화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.32, No.10, 1993-1998, October, 2015
DOI10.1007/s11814-015-0046-6  Export Citation
Fischer-Tropsch synthesis on Co-Al2O3-(promoter)/ZSM5 hybrid catalysts for the production of gasoline range hydrocarbons
Jae-Hong Ryu†, Suk-Hwan Kang, Jin-Ho Kim, Yun-Jo Lee1, and Ki-Won Jun1
  • Plant Engineering Center, Institute for Advances Engineering (IAE), Suwon 443-749, Korea
  • 1Petroleum Displacement Technology Research Center, Korea Research Institute of Chemical Technology (KRICT), P. O. Box 107, Sinseong-ro 19, Yuseong, Daejeon 305-600, Korea
E-mail:
The Fischer-Tropsch synthesis (FTS) reaction was investigated for the direct production of gasoline range hydrocarbons (C5-C9) from syngas on Ru-, Pt- and La-promoted Co-Al2O3/ZSM-5 (Si/Al=25) hybrid catalysts prepared by co-precipitation method in a slurry. The hybrid catalysts were characterized by BET surface area, XRD, H2-TPR and NH3-TPD analyses. Their physicochemical properties were correlated with the activity and selectivity of the catalysts. The promoted Co-Al2O3-(promoter)/ZSM-5 hybrid catalysts were superior to the unpromoted Co-Al2O3/ZSM-5 catalyst in terms of better C5-C9 yield. In particular, the Co-Al2O3-Pt/ ZSM-5 hybrid catalyst exhibited the highest catalytic activity with a low C1 and olefin selectivity and a high C5-C9 selectivity. It could be due to not only a higher value for the reduction degree by H2-TPR, but also assigned to weak acidic sites of a low temperature desorption peak by NH3-TPD.
Keywords:Fischer-Tropsch Synthesis;Cobalt Hybrid Catalyst;Promoter;Gasoline;ZSM-5;Syngas
  1. Keshav TR, Basu S, Fuel Process. Technol., 88(5), 493 (2007)
  2. Dry ME, Catal. Today, 71(3-4), 227 (2002)
  3. Kang SH, Ryu JH, Kim JH, Prasad PS, Bae JW, Cheon JY, Jun KW, Catal. Lett., 141(10), 1464 (2011)
  4. Liu ZW, Li XH, Asami K, Fujimoto K, Fuel Process. Technol., 88(2), 165 (2007)
  5. Yang GH, He JJ, Yoneyama Y, Tan YS, Han YZ, Tsubaki N, Appl. Catal. A: Gen., 329, 99 (2007)
  6. Bao J, He J, Zhang Y, Yoneyama Y, Tsubaki N, Angew. Chem.-Int. Edit., 47, 353 (2008)
  7. Li XG, He JJ, Meng M, Yoneyama Y, Tsubaki N, J. Catal., 265(1), 26 (2009)
  8. He JJ, Yoneyama Y, Xu BL, Nishiyama N, Tsubaki N, Langmuir, 21(5), 1699 (2005)
  9. Jacobs G, Das TK, Zhang YQ, Li JL, Racoillet G, Davis BH, Appl. Catal. A: Gen., 233(1-2), 263 (2002)
  10. Iglesia E, Appl. Catal. A: Gen., 161(1-2), 59 (1997)
  11. Storsaeter S, Borg O, Blekkan EA, Holmen A, J. Catal., 231(2), 405 (2005)
  12. Bezemer GL, Bitter JH, Kuipers HPCE, Oosterbeek H, Holewijn JE, Xu XD, Kapteijn F, van Dillen AJ, de Jong KP, J. Am. Chem. Soc., 128(12), 3956 (2006)
  13. Jacobs G, Ji YY, Davis BH, Cronauer D, Kropf AJ, Marshall CL, Appl. Catal. A: Gen., 333(2), 177 (2007)
  14. Schanke D, Vada S, Blekkan EA, Hilmen AM, Hoff A, Holmen A, J. Catal., 156(1), 85 (1995)
  15. Vada S, Hoff A, Adnanes E, Schanke D, Holemen A, Top. Catal., 2, 155 (1995)
  16. Guczi L, Bazin D, Kovacs I, Borko L, Schay Z, Lynch J, Parent P, Lafon C, Sterfler G, Koppany Z, Sajo I, Top. Catal., 20, 129 (2002)
  17. Girardon JS, Quinet E, Griboval-Constant A, Chernavskii PA, Gengembre L, Khodakov AY, J. Catal., 248, 143 (1995)
  18. Xu DY, Li WZ, Duan HM, Ge QJ, Xu HY, Catal. Lett., 102(3-4), 229 (2005)
  19. Hosseini SA, Taeb A, Feyzi F, Yaripour F, Catal. Commun., 5, 137 (2004)
  20. Bertole CJ, Mims CA, Kiss G, J. Catal., 221(1), 191 (2004)
  21. Faroldi BM, Lombardo EA, Cornaglia LM, Appl. Catal. A: Gen., 369(1-2), 15 (2009)
  22. Vidal H, Bernal S, Baker RT, Cifredo GA, Finol D, Rodriguez-Izquierdo JM, Appl. Catal. A: Gen., 208(1-2), 111 (2001)
  23. Boukha Z, Fitian L, Lopez-Haro M, Mora M, Ruiz JR, Jimenez-Sanchidrian C, Blanco G, Calvino JJ, Cifredo GA, Trasobares S, Bernal S, J. Catal., 272(1), 121 (2010)
  24. Guczi L, Kiricsi I, Appl. Catal., 186, 375 (1999)
  25. Bolder FHA, Energy Fuels, 21(3), 1396 (2007)
  26. Li YP, Wang TJ, Wu CZ, Lv YX, Tsubaki N, Energy Fuels, 22(3), 1897 (2008)
  27. Kang SH, Ryu JH, Kim JH, Jang IH, Kim AR, Han GY, Bae JW, Ha KS, Energy Fuels, 26(10), 6061 (2012)
  28. Storsaeter S, Totdal B, Walmsley JC, Tanem BS, Holmen A, J. Catal., 236(1), 139 (2005)
  29. Song SH, Lee SB, Bae JW, Prasad PSS, Jun KW, Catal. Commun., 9, 2282 (2008)
  30. Cheon JY, Kang SH, Bae JW, Park SJ, Jun KW, Dhar GM, Lee KY, Catal. Lett., 134(3-4), 233 (2010)
  31. Kang SH, Bae JW, Prasad PSS, Jun KW, Catal. Lett., 125(3-4), 264 (2008)
  32. Chu W, Chernavskii PA, Gengembre L, Pankina GA, Fongarland P, Khodakov AY, J. Catal., 252(2), 215 (2007)