Double-imprinted potentiometric sensors based on ligand exchange for the determination of dimethoate

Eyup Bektasoglu; Ebru Birlik Ozkutuk; Arzu Ersoz; Rıdvan Say

Korean Journal of Chemical Engineering, Vol.32, No.8, 1613-1617, August, 2015

DOI10.1007/s11814-014-0386-7 Export Citation

Double-imprinted potentiometric sensors based on ligand exchange for the determination of dimethoate

Eyup Bektasoglu, Ebru Birlik Ozkutuk^†, Arzu Ersoz¹, and Rıdvan Say¹

Department of Chemistry, Eskişehir Osmangazi University, Eskisehir, Turkey
¹Department of Chemistry, Eskisehir Osmangazi University, Eskisehir, Turkey

E-mail:

This paper describes a dimethoate imprinted polymeric potentiometric sensor for the determination of dimethoate that was designed by dispersing the dimethoate-imprinted polymer in dibutyl phthalate plasticizer and then embedded in polyvinyl chloride matrix. The method is based on molecularly imprinted polymer (MIP), which can be synthesized by using dimethoate as a template molecule, chitosan-Cd(II), and 3-mercaptopropyl-trimethoxysilane as a functional monomer and TEOS, and ephychlorohydrin as a cross-linking agent. We have studied a method for the selective binding behavior of dimethoate compounds on the surface of imprinted polymers which is prepared using ligand-exchange (LE) (chitosan-Cd(II)) monomer. The MIP-LE-1 and MIP-LE-2 based membranes have shown a detection limit of 4.3×10.6mmolL.1 and 3.5.10.5 mmolL.1, respectively. The sensor has exhibited a response time of 35min for MIP-LE-1 and 120min for MIP-LE-2. They are stable for more than three months.

Keywords:Potentiometric Sensor;Dimethoate;Mip;Ion Selective Electrode;Pesticide

[References]

Fan ZL, Yang GL, Liu HY, Chin. J. Chromatogr., 21, 199 (2003)
Vallano PT, Remcho VT, J. Chromatogr. A, 887, 125 (2000)
Qin L, He XW, Zhang W, Li WY, Zhang YK, J. Chromatogr. A, 1216, 807 (2009)
Lavignac N, Allender CJ, Brain KR, Anal. Chem. Acta, 510, 139 (2004)
Metcalf JS, Chem. Res. Toxicol., 16, 103 (2003)
Jegourel D, Delepee R, Breton F, Rolland A, Vidal R, Agrofoglio LA, Bioorgan. Med. Chem., 16, 8932 (2008)
Yin JF, Yang GL, Chen Y, J. Chromatogr. A, 1090, 68 (2005)
Tan Y, Peng H, Liang C, Yao S, Sens. Actuators B-Chem., 73, 179 (2001)
Chen YC, Brazier JJ, Yan MD, Bargo PR, Prahl SA, Sens. Actuators B-Chem., 102, 107 (2004)
Thoelen R, Vansweevelt R, Duchateau J, Horemans F, D’Haen J, Lutsen L, Vanderzande D, Ameloot M, vandeVen M, Cleij TJ, Wagner P, Biosens. Bioelectron., 23, 913 (2008)
Mazzotta E, Picca RA, Malitesta C, Piletsky SA, Piletska EV, Biosens. Bioelectron., 23, 1152 (2008)
Dai S, Burleigh MC, Ju YH, Gao HJ, Lin JS, Pennycook SJ, Barnes CE, Xue ZL, J. Am. Chem. Soc., 122(5), 992 (2000)
Lu YK, Yan XP, Anal. Chem., 76, 453 (2004)
Holthoff EL, Bright FV, Anal. Chim. Acta, 594, 147 (2007)
Shughart EL, Ahsan K, Detty MR, Bright FV, Anal. Chem., 78, 3165 (2006)
Piletskaya EV, Romero-Guerra M, Chianella I, Karim K, Turner APE, Piletsky SA, Anal. Chim. Acta, 542, 47 (2005)
Piletsky SA, Turner APF, Electroanalysis, 14(5), 317 (2002)
Henry OYF, Cullen DC, Piletsky SA, Anal. Bioanal. Chem., 382, 947 (2005)
Prasad K, Prathish KP, Gladis JM, Naidu GRK, Rao TP, Sens. Actuators B-Chem., 123, 65 (2007)
Vishnuvardhan V, Prathish KP, Naidu GRK, Rao TP, Electrochim. Acta, 52(24), 6922 (2007)
Sadeghi S, Fathi F, Abbasifar J, Sens. Actuators B-Chem., 122, 158 (2007)
Prathish KP, Prasad K, Rao TP, Suryanarayana MVS, Acid Talanta, 71, 1976 (2007)
D’Agostino G, Alberti G, Biesuz R, Pesavento M, Biosens. Bioelectron., 22, 145 (2006)
Zhou Y, Yu B, Levon K, Acid. Biosens. Bioelectron., 20, 1851 (2005)
Zhou Z, Yu B, Levon K, Chem. Mater., 15, 2774 (2003)
Lahav M, Kharitonov AB, Katz O, Kunitake T, Willner I, Anal. Chem., 73, 720 (2001)
Pogorelova SP, Bourenko T, Kharitonov AB, Willner I, The Analyst, 127, 1484 (2002)
Javanbakht M, Eynollahi S, Abdouss M, Ganjali MR, Norouzi CP, Safaraliee L, Electroanalysis, 20, 2023 (2008)
Erdem M, Say R, Ersoz A, Denizli A, Turk H, Appl. Clay Sci., 47, 223 (2010)
Odabasi M, Say R, Denizli A, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 27, 90 (2007)
Umezawa Y, Umezawa K, Sato H, Pure Appl. Chem., 67, 507 (1995)
Imato T, Ishibashi N, Biosens. Bioelectron., 10, 435 (1995)
Khaleda E, Hassana HNA, Mohamed GG, Ragabc FA, Eldin AA, Talanta, 83, 357 (2010)
Mulchandani P, Mulchandani A, Kaneva I, Chen W, Biosens. Bioelectron., 14, 77 (1999)

[Referenced By]

[1] Fan ZL, Yang GL, Liu HY, Chin. J. Chromatogr., 21, 199 (2003)

[2] Vallano PT, Remcho VT, J. Chromatogr. A, 887, 125 (2000)

[3] Qin L, He XW, Zhang W, Li WY, Zhang YK, J. Chromatogr. A, 1216, 807 (2009)

[4] Lavignac N, Allender CJ, Brain KR, Anal. Chem. Acta, 510, 139 (2004)

[5] Metcalf JS, Chem. Res. Toxicol., 16, 103 (2003)

[6] Jegourel D, Delepee R, Breton F, Rolland A, Vidal R, Agrofoglio LA, Bioorgan. Med. Chem., 16, 8932 (2008)

[7] Yin JF, Yang GL, Chen Y, J. Chromatogr. A, 1090, 68 (2005)

[8] Tan Y, Peng H, Liang C, Yao S, Sens. Actuators B-Chem., 73, 179 (2001)

[9] Chen YC, Brazier JJ, Yan MD, Bargo PR, Prahl SA, Sens. Actuators B-Chem., 102, 107 (2004)

[10] Thoelen R, Vansweevelt R, Duchateau J, Horemans F, D’Haen J, Lutsen L, Vanderzande D, Ameloot M, vandeVen M, Cleij TJ, Wagner P, Biosens. Bioelectron., 23, 913 (2008)

[11] Mazzotta E, Picca RA, Malitesta C, Piletsky SA, Piletska EV, Biosens. Bioelectron., 23, 1152 (2008)

[12] Dai S, Burleigh MC, Ju YH, Gao HJ, Lin JS, Pennycook SJ, Barnes CE, Xue ZL, J. Am. Chem. Soc., 122(5), 992 (2000)

[13] Lu YK, Yan XP, Anal. Chem., 76, 453 (2004)

[14] Holthoff EL, Bright FV, Anal. Chim. Acta, 594, 147 (2007)

[15] Shughart EL, Ahsan K, Detty MR, Bright FV, Anal. Chem., 78, 3165 (2006)

[16] Piletskaya EV, Romero-Guerra M, Chianella I, Karim K, Turner APE, Piletsky SA, Anal. Chim. Acta, 542, 47 (2005)

[17] Piletsky SA, Turner APF, Electroanalysis, 14(5), 317 (2002)

[18] Henry OYF, Cullen DC, Piletsky SA, Anal. Bioanal. Chem., 382, 947 (2005)

[19] Prasad K, Prathish KP, Gladis JM, Naidu GRK, Rao TP, Sens. Actuators B-Chem., 123, 65 (2007)

[20] Vishnuvardhan V, Prathish KP, Naidu GRK, Rao TP, Electrochim. Acta, 52(24), 6922 (2007)

[21] Sadeghi S, Fathi F, Abbasifar J, Sens. Actuators B-Chem., 122, 158 (2007)

[22] Prathish KP, Prasad K, Rao TP, Suryanarayana MVS, Acid Talanta, 71, 1976 (2007)

[23] D’Agostino G, Alberti G, Biesuz R, Pesavento M, Biosens. Bioelectron., 22, 145 (2006)

[24] Zhou Y, Yu B, Levon K, Acid. Biosens. Bioelectron., 20, 1851 (2005)

[25] Zhou Z, Yu B, Levon K, Chem. Mater., 15, 2774 (2003)

[26] Lahav M, Kharitonov AB, Katz O, Kunitake T, Willner I, Anal. Chem., 73, 720 (2001)

[27] Pogorelova SP, Bourenko T, Kharitonov AB, Willner I, The Analyst, 127, 1484 (2002)

[28] Javanbakht M, Eynollahi S, Abdouss M, Ganjali MR, Norouzi CP, Safaraliee L, Electroanalysis, 20, 2023 (2008)

[29] Erdem M, Say R, Ersoz A, Denizli A, Turk H, Appl. Clay Sci., 47, 223 (2010)

[30] Odabasi M, Say R, Denizli A, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 27, 90 (2007)

[31] Umezawa Y, Umezawa K, Sato H, Pure Appl. Chem., 67, 507 (1995)

[32] Imato T, Ishibashi N, Biosens. Bioelectron., 10, 435 (1995)

[33] Khaleda E, Hassana HNA, Mohamed GG, Ragabc FA, Eldin AA, Talanta, 83, 357 (2010)

[34] Mulchandani P, Mulchandani A, Kaneva I, Chen W, Biosens. Bioelectron., 14, 77 (1999)