화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.27, 283-290, July, 2015
DOI10.1016/j.jiec.2015.01.002  Export Citation
Modification of PES membrane by PEG-coated cobalt doped iron oxide for improved Cu(II) removal
Kian Hwa Chan, Ee Ting Wong, Ani Idris†, and Noordin Mohd Yusof1
  • Department of Bioprocess Engineering, Faculty of Chemical Engineering, c/o Institute of Bioproduct Development, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • 1Department of Manufacturing and Industrial Engineering, Faculty of Mechanical Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
E-mail:
Modification of membranes using nanoparticles is another latest trend in membrane technology. In this work, the hydrophobic cobalt(II) doped iron oxide nanoparticles were coated with polyethylene glycol of molecular weight 600 so as to prevent their agglomeration thus improving their dispersion when added into the dope solution containing 20 wt% of polyethersulfone in dimethylformamide. The nanomodified membranes were characterized in terms of flux permeation (Q), wetting ability, contact angle, pore size and solute rejection. These membranes were then used to remove Cu(II) and its separation efficiency was found to improve significantly.
Keywords:Cobalt(II) doped iron oxide;Modified PES ultrafiltration membrane;Nanomodification;Cu(II) rejection
  1. Negm NA, Sheikh RE, El-Farargy AF, Hefni HHH, Bekhit M, J. Ind. Eng. Chem., 21, 526 (2015)
  2. Ge Y, Li Z, Xiao D, Xiong P, Ye N, J. Ind. Eng. Chem., 20(4), 1765 (2014)
  3. Fu F, Wang Q, J. Environ. Manage., 92, 407 (2011)
  4. Ferella F, Prisciandaro M, De Michelis I, Veglio F, Desalination, 207(1-3), 125 (2007)
  5. Barakat MA, Schmidt E, Desalination, 256(1-3), 90 (2010)
  6. Lee ME, Park JH, Chung JW, Lee CY, Kang S, J. Ind. Eng. Chem., 21, 470 (2015)
  7. Yang J, Yu M, Chen W, J. Ind. Eng. Chem., 21, 414 (2015)
  8. Largitte L, Lodewyckx P, J. Environ. Chem. Eng., 2, 788 (2014)
  9. Habibi N, Karimi B, J. Ind. Eng. Chem., 20(5), 3033 (2014)
  10. Debnath S, Kitinya J, Onyango MS, J. Ind. Eng. Chem., 20(4), 2119 (2014)
  11. Khatiri R, Reyhani A, Mortazavi SZ, Hossainalipour M, J. Ind. Eng. Chem., 19(5), 1642 (2013)
  12. Mittal H, Ballav N, Mishra SB, J. Ind. Eng. Chem., 20(4), 2184 (2014)
  13. Burks T, Avila M, Akhtar F, Gothelid M, Lansaker PC, Toprak MS, Muhammed M, Uheida A, J. Colloid Interface Sci., 425, 36 (2014)
  14. Ahmad R, Kumar R, Haseeb S, Arab. J. Chem., 5, 353 (2012)
  15. Basu T, Ghosh UC, J. Ind. Eng. Chem., 17(5-6), 834 (2011)
  16. Park YI, Piao Y, Lee N, Yoo B, Kim BH, Choi SH, Hyeon T, J. Mater. Chem., 31, 11472 (2011)
  17. Woo K, Hong J, IEEE Trans. Magn., 41, 4137 (2005)
  18. Liu F, Abed MRM, Li K, J. Membr. Sci., 366(1-2), 97 (2011)
  19. Hong JM, He Y, Desalination, 302, 71 (2012)
  20. Liang HQ, Wu QY, Wan LS, Huang XJ, Xu ZK, J. Membr. Sci., 465, 56 (2014)
  21. Qu JB, Shao HH, Jing GL, Huang F, Colloids Surf. B: Biointerfaces, 102, 37 (2013)
  22. Hu T, Dong GX, Li HY, Chen V, J. Membr. Sci., 432, 13 (2013)
  23. Rahman MM, Filiz V, Shishatskiy S, Abetz C, Neumann S, Bolmer S, Khan MM, Abetz V, J. Membr. Sci., 437, 286 (2013)
  24. Long X, Meng Q, Sha R, Huang Q, Zhang G, J. Membr. Sci., 409-410, 105 (2012)
  25. Prince JA, Bhuvana S, Boodhoo KVK, Anbharasi V, Singh G, J. Membr. Sci., 454, 538 (2014)
  26. Chakrabarti S, Mandal SK, Chaudhuri S, Nanotechnology, 16, 506 (2005)
  27. Kee CM, Idris A, Sep. Purif. Technol., 75(2), 102 (2010)
  28. Chan KH, Wong ET, Khan MI, Idris A, Yusof NM, J. Ind. Eng. Chem., 20(5), 3744 (2014)
  29. Han YJ, Wang KH, Lai JY, Liu YL, J. Membr. Sci., 463, 17 (2014)
  30. Singh S, Khulbe KC, Matsuura T, Ramamurthy P, J. Membr. Sci., 142(1), 111 (1998)
  31. Comerton AM, Andrews RC, Bagley DM, J. Membr. Sci., 327(1-2), 155 (2009)
  32. Idris A, Ahmed I, Misran M, Desalination, 249(2), 541 (2009)
  33. Yuliwati E, Ismail AF, Matsuura T, Kassim MA, Abdullah MS, Desalination, 283, 206 (2011)
  34. Moghimifar V, Raisi A, Aroujalian A, J. Membr. Sci., 461, 69 (2014)
  35. Jia ZQ, Tian CN, Desalination, 247(1-3), 423 (2009)
  36. Idris A, Zain NM, Noordin MY, Desalination, 207(1-3), 324 (2007)
  37. Noor NDM, Yusof NM, Ahmed I, Hesampour M, Idris A, J. Appl. Polym. Sci., 128(3), 1746 (2013)
  38. Mosqueda-Jimenez DB, Narbaitz RM, Matsuura T, Chowdhury G, Pleizier G, Santerre JP, J. Membr. Sci., 231(1-2), 209 (2004)
  39. Aksu Z, Oglu IAI, Process Biochem., 40, 3031 (2005)
  40. Shan Z, Yang WS, Zhang X, Huang QM, Ye H, J. Braz. Chem. Soc., 18, 1329 (2007)
  41. Cui H, Ren W, Wang W, J. Sol-Gel Sci. Technol., 54, 37 (2010)
  42. Manigandan R, Giribabu K, Suresh R, Vijayalakshmi L, Stephen A, Narayanan V, Chem. Sci. Trans., 2, S47 (2013)
  43. Zhang B, Su H, Gu X, Zhang Y, Wang P, Li X, Zhang X, Wang H, Yang X, Zeng S, Catal. Sci. Technol., 3, 2639 (2013)
  44. Cheng G, Fan X, Tian W, Liu Y, Liu G, J. Polym. Res., 17, 529 (2010)
  45. Taniguchi M, Kilduff JE, Belfort G, J. Membr. Sci., 222(1-2), 59 (2003)
  46. Barth C, Goncalves MC, Pires ATN, Roeder J, Wolf BA, J. Membr. Sci., 169(2), 287 (2000)
  47. Choi JH, Jegal J, Kim WN, J. Membr. Sci., 284(1-2), 406 (2006)