화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.27, 164-174, July, 2015
DOI10.1016/j.jiec.2014.12.031  Export Citation
Synergic adsorption of acid blue 80 and heavy metal ions (Cu2+/Ni2+) onto activated carbon and its mechanisms
Xinsheng Luo, Zhe Zhang, Pengxin Zhou, Yani Liu1, Guofu Ma, and Ziqiang Lei†
  • Key Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China
  • 1College of Science, Gansu Agricultural University, Lanzhou 730070, China
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A novel synergic adsorption process of acid blue 80 dye (AB80) and heavy metal ions (Cu2+ or Ni2+) on a low-cost activated carbon (PRAC) which was prepared from potato residue was reported. The results indicated that the maximum adsorption capacity of PRAC for AB80 and Cu2+ were 294.7 mg/g and 45.0 mg/g in the AB80-Cu2+ system, respectively. In the mono-component system, the values were 173.0 mg/g and 26.8 mg/g, respectively. Compared with mono-component system, the AB80 and Cu2+ showed good synergistic effect on PRAC. The similarly result was revealed in the AB80-Ni2+ system. For a binary system, the adsorption isotherm of AB80 and heavy metal ions followed the non-modified Sips model, and the adsorption kinetic models followed the pseudo-second order kinetic model. The effect of pH also was discussed, and showed significant role in the binary-component system adsorption. The selectivity in synergic adsorption was discussed. BET, FE-SEM/EDX and XPS were used to characterize PRAC with and without adsorbed dye and heavy metal ions, possible mechanisms of AB80 and heavy metal ions synergic adsorption process were proposed.
Keywords:Acid blue 80;Synergic adsorption;Mechanism;Heavy metal;Activated carbon
  1. Davila-Jimenez MM, Elizalde-Gonzalez MP, Hernandez-Montoya V, Bioresour. Technol., 100(24), 6199 (2009)
  2. Bestani B, Benderdouche N, Benstaali B, Belhakem M, Addou A, Bioresour. Technol., 99(17), 8441 (2008)
  3. Benadjemia M, Milliere L, Reinert L, Benderdouche N, Duclaux L, Fuel Process. Technol., 92(6), 1203 (2011)
  4. Wang L, Zhang JP, Wang AQ, Desalination, 266(1-3), 33 (2011)
  5. CatherineTee PN, JaniceWong YT, Sherry JP, Bols NC, Ecotoxicol. Environ. Saf., 74, 1874 (2011)
  6. Aguayo-Villarreal IA, Hernandez-Montoya V, Bonilla-Petriciolet A, Tovar-Gomez R, Ramırez-Lopez EM, Montes-Moran MA, Dyes Pigment., 96, 459 (2013)
  7. Fu FL, Wang Q, J. Environ. Manage., 92, 407 (2011)
  8. Wang SB, Soudi M, Li L, Zhu ZH, J. Hazard. Mater., 133(1-3), 243 (2006)
  9. Panswed T, Wongchaisuwan S, Water Sci. Technol., 18, 139 (1986)
  10. Ciardelli G, Corsi L, Marucci M, Resour. Conserv. Recycl., 31, 189 (2000)
  11. Korbahti BK, Artut K, Gecgel C, Ozer A, Chem. Eng. J., 173(3), 677 (2011)
  12. Bilgic C, J. Colloid Interface Sci., 281(1), 33 (2005)
  13. Tong XJ, Li JY, Yuan JH, Xu RK, Chem. Eng. J., 172(2-3), 828 (2011)
  14. Roy A, Adhikari B, Majumder SB, Ind. Eng. Chem. Res., 52(19), 6502 (2013)
  15. Alslaibi TM, Abustan I, Ahmad MA, Abu Foul A, J. Chem. Technol. Biotechnol., 88(7), 1183 (2013)
  16. Rafatullah M, Sulaiman O, Hashim R, Ahmad A, J. Hazard. Mater., 177(1-3), 70 (2010)
  17. Marsh H, Rodriguez-Reinoso F, Activated carbon, Elsevier Science & Technology Books, New York, 2006, pp. 15-54.
  18. Hanzlık J, Jehlicka J, Sebek O, Weishauptova Z, Machovic V, Water Res., 38, 2178 (2004)
  19. Li LJ, Liu FQ, Jing XS, Ling PP, Li AM, Water Res., 45, 1177 (2011)
  20. Matsui Y, Yoshida T, Nakao S, Knappe DRU, Matsushita T, Water Res., 46, 4741 (2012)
  21. Padilla-Ortega E, Leyva-Ramos R, Flores-Cano JV, Chem. Eng. J., 225, 535 (2013)
  22. Porter JF, McKay G, Choy KH, Chem. Eng. Sci., 54(24), 5863 (1999)
  23. Papageorgiou SK, Katsaros FK, Kouvelos EP, Kanellopoulos NK, J. Hazard. Mater., 162(2-3), 1347 (2009)
  24. Yang LJ, Zhang YY, Liu XY, Jiang XQ, Zhang ZZ, Zhang TT, Zhang L, Chem. Eng. J., 246, 88 (2014)
  25. Yan YK, Xiang B, Yi XW, Li YJ, Jia Q, J. Appl. Polym. Sci., http://dx.doi.org/10.1002/APP.41168. (2014)
  26. Issa AA, Al-Degs YS, Al-Ghouti MA, Olimat AAM, Chem. Eng. J., 240, 554 (2014)
  27. Ghaedi M, Mosallanejad N, J. Ind. Eng. Chem., 20(3), 1085 (2014)
  28. Hajati S, Ghaedi M, Karimi F, Barazesh B, Sahraei R, Daneshfar A, J. Ind. Eng. Chem., 20(2), 564 (2014)
  29. Tovar-Gomeza R, Rivera-Ramıreza DA, Hernandez-Montoyaa V, Bonilla-Petriciolet A, Duran-Valleb CJ, Montes-Moranc MA, J. Hazard. Mater., 199-200, 290 (2012)
  30. Tovar-Gomez R, Moreno-Virgen MR, Moreno-Perez J, Bonilla-Petriciolet A, Hernandez-Montoya V, Duran-Valle CJ, Chem. Eng. Res. Des., http://dx.doi.org/10.1016/j.cherd.07.012. (2014)
  31. Ling C, Liu FQ, Long C, Chen TP, Wu QY, Li AM, Chem. Eng. J., 236, 323 (2014)
  32. Jiang J, Xua RK, Jiang TY, Li Z, J. Hazard. Mater., 229-230, 145 (2012)
  33. Noroozi B, Sorial GA, J. Environ. Sci., 25, 419 (2013)
  34. Al-Asheh S, Banat F, Al-Omari R, Duvnjak Z, Chemosphere, 41, 659 (2000)
  35. Pagnanelli F, Esposito A, Veglio F, Water Res., 36, 4095 (2002)
  36. Alslaibi TM, Abustan I, Ahmad MA, Foul AA, J. Dispersion Sci. Technol., 35, 913 (2014)
  37. Alslaibi TM, Abustan I, Ahmad MA, Foul AA, Desalin. Water Treat., 52, 7887 (2014)
  38. Srivastava VC, Mall ID, Mishra IM, Colloids Surf. A: Physicochem. Eng. Asp., 312, 172 (2008)
  39. Alslaibi TM, Abustan I, Ahmad MA, Foul AA, J. Environ. Chem. Eng., 1, 589 (2013)
  40. Hameed BH, Ahmad AA, Aziz N, Chem. Eng. J., 133(1-3), 195 (2007)
  41. Kinraide TB, Yermiyahu U, J. Inorg. Biochem., 101, 1201 (2007)
  42. Misono M, Ochiai E, Saito Y, Yoneda Y, J. Inorg. Nucl. Chem., 29, 2685 (1967)
  43. Alslaibi TM, Abustan I, Ahmad MA, Foul AA, Desalin. Water Treat., http://dx.doi.org/10.1080/19443994.2013.876672.
  44. Alslaibi TM, Abustan I, Ahmad MA, Foul AA, Environ. Prog. Sustain., 33, 1074 (2014)
  45. Hadi M, Samarghandi MR, Mckay G, Chem. Eng. J., 160(2), 408 (2010)
  46. Shukla SR, Pai RS, Sep. Purif. Technol., 43(1), 1 (2005)
  47. Zou WH, Bai HJ, Gao SP, J. Chem. Eng. Data, 57(10), 2792 (2012)
  48. Zhu J, Deng B, Yang J, Gang D, Carbon, 47, 2014 (2009)
  49. Pan B, Zhang Q, Du W, Zhang W, Pan B, Zhang Q, Xu Z, Zhang Q, Water Res., 41, 3103 (2007)
  50. Hsieh CT, Teng H, Chen WY, Cheng YS, Carbon, 48, 4219 (2010)
  51. Manu V, Mody HM, Bajaj HC, Jasra RV, Ind. Eng. Chem. Res., 48(19), 8954 (2009)
  52. Vargas AMM, Cazetta AL, Kunita MH, Silva TL, Almeida VC, Chem. Eng. J., 168(2), 722 (2011)