Thermo-responsive and magnetic molecularly imprinted Fe3O4@carbon nanospheres for selective adsorption and controlled release of 2,4,5-trichlorophenol

Jixiang Wang; Jianming Pan; Yijie Yin; Runrun Wu; Xiaohui Dai; Jiangdong Dai; Lin Gao; Hongxiang Ou

Journal of Industrial and Engineering Chemistry, Vol.25, 321-328, May, 2015

DOI10.1016/j.jiec.2014.11.011 Export Citation

Thermo-responsive and magnetic molecularly imprinted Fe3O4@carbon nanospheres for selective adsorption and controlled release of 2,4,5-trichlorophenol

Jixiang Wang, Jianming Pan^†, Yijie Yin, Runrun Wu, Xiaohui Dai^†, Jiangdong Dai, Lin Gao, and Hongxiang Ou¹

School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, China
¹School of Environmental and Safety Enginerring, Changzhou University, Changzhou, 213164, China

E-mail:,

Thermal-responsive and magnetic molecularly imprinted polymers (TMMIPs) based on Fe3O4@carbon (Fe3O4@C) were prepared by free radical polymerization and applied to selective adsorption and controlled release of 2,4,5-trichlorophenol (2,4,5-TCP) from aqueous solution. TMMIPs were composed of multilayer structure, and exhibited magnetic sensitivity, magnetic stability and thermal stability (especially below the. The reversible transform of mean diameter resulted from the change of testing temperature, indicating the thermo-responsive properties of TMMIPs. Selective adsorption and controlled release of 2,4,5-TCP were also investigated at 25 °C and higher temperature (such as 45 °C and 60 °C), respectively.

Keywords:Thermal-responsive and magnetic molecularly imprinted polymers;Fe3O4@carbon nanospheres;2,4,5-Trichlorophenol;Selective adsorption;Controlled release

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[2] Piringer G, Bhattacharya SK, Water Res., 33, 2674 (1999)

[3] Laszlo K, Podkoscielny P, Dabrowski A, Langmuir, 19(13), 5287 (2003)

[4] Quaglia M, Sellergren B, Lorenzi ED, J. Chromatogr. A, 1044, 53 (2004)

[5] Alexander C, Andersson HS, Andersson LI, Ansell RJ, Kirsch N, Nicholls IA, O’Mahony J, Whitcombe MJ, J. Mol. Recognit., 19, 106 (2006)

[6] Sharabi D, Paz Y, Appl. Catal. B: Environ., 95(1-2), 169 (2010)

[7] Benito-Pnena E, Urraca JL, Sellergren B, Moreno-Bondı MC, J. Chromatogr. A, 1208, 62 (2008)

[8] Valero-Navarroa A, Gomez-Romero M, Fernandez-Sanchez JF, Cormack PAG, Segura-Carretero A, Fernandez-Gutierrez A, J. Chromatogr. A, 1218, 7289 (2011)

[9] Plewa A, Yusa S, Szuwarzynski M, Szczubiałka K, Morishima Y, Nowakowska M, J. Med. Chem., 55, 8712 (2012)

[10] Xing XP, Liu S, Yu JH, Lian WJ, Huang JD, Biosens. Bioelectron., 31, 277 (2012)

[11] Zhu R, Zhao WH, Zhai MJ, Wei FD, Cai Z, Sheng N, Hu Q, Anal. Chim. Acta, 658, 209 (2010)

[12] Shiomi T, Matsui M, Mizukami F, Sakaguchi K, Biomaterials, 26, 5564 (2005)

[13] Pan JM, Xu LC, Dai JD, Li XX, Hang H, Huo PW, Li CX, Yan YS, Chem. Eng. J., 174(1), 68 (2011)

[14] Hua ZD, Chen ZY, Li YZ, Zhao MP, Langmuir, 24(11), 5773 (2008)

[15] Yu HY, Li W, Zhou J, Gu JS, Huang L, Tang ZQ, Wei XW, J. Membr. Sci., 343(1-2), 82 (2009)

[16] Akar E, Altınıs A, Seki Y, Carbohydr. Polym., 90, 1634 (2012)

[17] Chen CJ, Jin Q, Liu GY, Li DD, Wang JL, Ji J, Polymer, 53(17), 3695 (2012)

[18] Kokufuta E, Yamauchi T, Osadab Y, Polym. Gels Networks, 3, 397 (1995)

[19] Jing T, Du HR, Dai Q, Xia H, Niu JW, Hao QL, Mei SR, Zhou YK, Biosens. Bioelectron., 26, 301 (2010)

[20] Wang LY, Sun Y, Wang J, Wang J, Yu AM, Zhang HQ, Song DQ, Colloids Surf. B: Biointerfaces, 84, 484 (2011)

[21] Minati L, Speranza G, Bernagozzi I, Torrengo S, Toniutti L, Rossi B, Ferrari M, Chiasera A, J. Phys. Chem. C, 114, 11068 (2010)

[22] Zhang L, Zhu H, Mater. Lett., 63, 272 (2009)

[23] Schild HG, Prog. Polym. Sci., 17, 163 (1992)

[24] Pan JM, Zou XH, Wang X, Guan W, Yan YS, Han JA, Chem. Eng. J., 162(3), 910 (2010)

[25] Grant TM, King CJ, Ind. Eng. Chem. Res., 29, 264 (1990)

[26] Mazzotti M, J. Chromatogr. A, 1126, 311 (2006)

[27] Allen SJ, Mckay G, Porter JF, J. Colloid Interface Sci., 280(2), 322 (2004)

[28] Soto ML, Moure A, Dominguez H, Parajo JC, J. Food Eng., 105(1), 1 (2011)

[29] Ho YS, McKay G, Water Res., 33, 578 (1999)

[30] Ho YS, McKay G, Process Biochem., 34(5), 451 (1999)

[31] Wu ZJ, Joo H, Lee K, Chem. Eng. J., 112(1-3), 227 (2005)

[32] Xu LC, Pan JM, Dai JD, Li XX, Hang H, Cao ZJ, Yan YS, J. Hazard. Mater., 223-234, 48 (2012)

[33] Li SJ, Ge Y, Piletsky SA, Turner APF, Adv. Funct. Mater., 21(17), 3344 (2011)