화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.22, 41-52, February, 2015
DOI10.1016/j.jiec.2014.06.023  Export Citation
Activity and stability of Au/CeO2.Fe2O3 catalysts for the hydrogen production via oxidative steam reforming of methanol
Chinchanop Pojanavaraphan, Umpawan Satitthai, Apanee Luengnaruemitchai†, and Erdogan Gulari1
  • The Petroleum and Petrochemical College, Chulalongkorn University, Bangkok 10330, Thailand
  • 1Department of Chemical Engineering, University of Michigan, MI, USA
E-mail:
The catalytic performance of Au/CeO2.Fe2O3 prepared by deposition.precipitation for oxidative steam reforming of methanol was investigated. It was found that the 3 wt% Au/CeO2.Fe2O3 with Ce/(Ce + Fe) = 0.25 calcined at 300 8C exhibited the highest methanol conversion and H2 concentration in the temperature range of 200.400 8C. The H2-TPR, XPS, and XRD studies suggested improvements in metal.metal, metal.support, and support.support interactions. The co-existence of free a-Fe2O3 and the Ce1-xFexO2 solid solution phases seemed to be necessary for high activity. Additionally, the Au/CeO2. Fe2O3 displayed a long life-time, even in the presence of coke deposition and transformation of the solid solution phase.
Keywords:Oxidative steam reforming;Methanol;Hydrogen;Au catalyst;Fe2O3
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