Synthesis, characterization and bactericidal property of chitosan-graft-polyaniline/montmorillonite/ZnO nanocomposite

Alireza Samzadeh-Kermani; Somayeh Miri

Korean Journal of Chemical Engineering, Vol.32, No.6, 1137-1141, June, 2015

DOI10.1007/s11814-014-0285-y Export Citation

Synthesis, characterization and bactericidal property of chitosan-graft-polyaniline/montmorillonite/ZnO nanocomposite

Alireza Samzadeh-Kermani^†, and Somayeh Miri

Department of Chemistry, Faculty of Science, University of Zabol, Zabol, Iran

E-mail:

We synthesized the nanocomposite of chitosan-graft-polyaniline/montmorillonite/zinc oxide (CTS-g-PANi/MMT/ZnO). ZnO nanoparticles (NPs) were successfully synthesized from ZnO powder in the Cts/MMT matrix, using traditional method. CTS-g-PANi co-polymer was synthesized in the presence of ammonium peroxydisulfate (APS). The CTS-g-PANi and MMT were used as the natural polymeric stabilizer and the solid support, respectively. The morphology and the particle size of ZnO NPs and synthesized nanocomposite were investigated by Fourier-transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD) analysis, and scanning electron microscopy (SEM). According to the XRD results, the nanoparticle size was found to be in the range of 22-35 nm. SEM images showed the hexagonal shape of ZnO NPs, which is suitable for the evaluation of antibacterial activity. Finally, the bactericidal property of prepared nanocomposites was also evaluated against the bacteria of Gram positive Staphylococcus aureus (Staph.) and Gram negative Escherichia coli (E. coli), using the paper disc diffusion method.

Keywords:ZnO Nanoparticles;Nanocomposites;Montmorillonite;Chitosan-grafted-polyaniline;Bactericidal

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[Referenced By]

[1] Zhou B, Balee R, Groenendaal R, Nanotechnol. L. Bus., 2, 222 (2005)

[2] Murphy CJ, J. Mater. Chem., 18, 2173 (2008)

[3] Singh S, Arya S, Pandey P, Malhotra B, Saha S, Sreenivas K, Gupta V, Appl. Phys. Lett., 91, 63901 (2007)

[4] Faria RMB, Cesar DB, Salim VMM, Catal. Today, 168, 133 (2008)

[5] Sun YW, Tsui YY, Opt. Mater., 29, 1111 (2007)

[6] Ren X, Chen D, Meng X, Tang F, Hou X, Han D, Zhang L, J. Colloid Interface Sci., 183, 334 (2009)

[7] Wang J, Liu P, Wang S, Han W, Wang X, Fu X, J. Mol. Catal. A-Chem., 21, 273 (2007)

[8] Renken A, Minsker LK, Adv. Catal., 47, 53 (2010)

[9] Anzlovar A, Orel ZC, Zigon M, Eur. Polym. J., 46, 1216 (2010)

[10] Garces HF, Galindo HM, Garces LJ, Hunt J, Morey A, Suib SL, Micropor, 127, 190 (2010)

[11] Kim KD, Han DN, Lee JB, Kim HT, Scr. Mater., 54, 143 (2006)

[12] Li WJ, Shi EW, Zheng YQ, Yin ZW, J. Mater. Sci. Lett., 20(15), 1381 (2001)

[13] Kim KD, Kim HT, J. Sol-Gel Sci. Technol., 25, 183 (2002)

[14] O'Regan B, Schwartz DT, Zakeeruddin SM, Gratzel M, Adv. Mater., 12(17), 1263 (2000)

[15] MacDiarmid AG, Angew. Chem.-Int. Edit., 40, 2581 (2001)

[16] Elsenbaumer RL, Reynolds JR, Skotheim TA, Handbook of Conducting Polymers, Marcel Dekker (1998).

[17] Kim SK, Mendis E, Food Res. Int., 39, 383 (2006)

[18] MNV RK, React. Funct. Polym., 46, 1 (2000)

[19] Ignatova M, Manolova N, Rashkov I, Eur. Polym. J., 43, 1112 (2007)

[20] Zhong Y, Wang SQ, J. Rheol., 47, 483 (2002)

[21] Zhao D, Zhou J, Liu N, Appl. Clay Sci., 33, 161 (2006)

[22] Nguyen QT, Baird DG, Adv. Polym. Technol., 25(4), 270 (2006)

[23] AbdElhady M, Int. J. Carbohyd. Chem., 6, 2012 (2012)

[24] Hwang JJ, Ma TW, Mater. Chem. Phys., 136(2-3), 613 (2012)

[25] Hosseini SH, Simiari J, Farhadpour B, Iran. Polym. J., 18, 3 (2009)

[26] Guo M, Diao P, Cai S, J. Solid State Chem., 178, 1864 (2005)

[27] Zhu JF, Zhu YJ, J. Phys. Chem. B, 110(17), 8593 (2006)