Thiazole derivatives as efficient corrosion inhibitor for oil-well tubular steel in hydrochloric acid solution

Mahendra Yadav; Dipti Sharma; Sumit Kumar

Korean Journal of Chemical Engineering, Vol.32, No.5, 993-1000, May, 2015

DOI10.1007/s11814-014-0275-0 Export Citation

Thiazole derivatives as efficient corrosion inhibitor for oil-well tubular steel in hydrochloric acid solution

Mahendra Yadav^†, Dipti Sharma, and Sumit Kumar

Department of Applied Chemistry, Indian School of Mines, Dhanbad 826004, India

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The effect of 1-(benzo[d]thiazol-2-yl)-3-chloro-4-(3,5-dichlorophenyl)-4-methylazetidin-2-one (BDMA) and 3-(benzo[d]thiazol-2-yl)-2-(3,5-dichlorophenyl)-2,5-dimethylthiazolidin-4-one (BDMT) on the corrosion of oil well tubular steel (N80 steel) in 15% hydrochloric acid solution was investigated by means of potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques. The surface morphology of the uninhibited and inhibited samples was studied with atomic force microscopy (AFM). The corrosion inhibition efficiency of both inhibitors increased with increasing inhibitors concentration. The adsorption of both inhibitor molecules on surface of N80 steel obeys Langmuir adsorption isotherm. Potentiodynamic polarization measurements indicated that both the studied inhibitors act as mixed type inhibitor. Quantum chemical calculations were carried out using density functional theory (DFT) to correlate the experimental results with the theoretical results.

Keywords:N80 Steel;Hydrochloric Acid;Corrosion Inhibition;EIS;AFM;Density Functional Theory

[References]

Yadav M, Behera D, Sharma U, Corros. Eng. Sci. Technol., 48, 19 (2013)
Vishwanatham S, Sinha PK, Anti-Corros. Methods Mater., 56, 139 (2009)
Bentiss F, Mernari B, Traisnel M, Vezin H, Lagrenee M, Corros. Sci., 53, 487 (2011)
Benali O, Larabi L, Traisnel M, Gengembre L, Harek Y, Appl. Surf. Sci., 253(14), 6130 (2007)
Bentiss F, Lebrini M, Lagrenee M, Corros. Sci., 47, 2915 (2005)
Cruz J, Martinez R, Genesca J, Garcia-Ochoa E, J. Electroanal. Chem., 566(1), 111 (2004)
Khaled KF, Electrochim. Acta, 48(17), 2493 (2003)
Mistry K, Desai KR, Indian J. Chem., 45, 1762 (2006)
Lee C, Yang W, Parr RG, Phys. Rev. B, 37, 785 (1988)
Wang X, Yang H, Wang F, Wang X, Yang H, Wang F, Corros. Sci., 53, 113 (2011)
Li WH, He Q, Zhang ST, Pei CL, Hou BR, J. Appl. Electrochem., 38(3), 289 (2008)
Ramesh S, Rajeswari S, Electrochim. Acta, 49(5), 811 (2004)
Ashassi-Sorkhabi H, Shaabani B, Seifzadeh D, Appl. Surf. Sci., 239(2), 154 (2005)
Behpour SM, Ghoreishi N, Mohammadi N, Soltani M, Corros. Sci., 52, 4046 (2010)
Solmaz R, Kardas G, Culha M, Yazici B, Erbil M, Electrochim. Acta, 53(20), 5941 (2008)
Ozcan M, Dehri I, Erbil M, Appl. Surf. Sci., 236(1-4), 155 (2004)
Lebrini M, Robert F, Lecante A, Roos C, Corros. Sci., 53, 687 (2011)
Dehri I, Ozcan M, Mater. Chem. Phys., 98(2-3), 316 (2006)
Ghareba S, Omanovic S, Electrochim. Acta, 56(11), 3890 (2011)
Machnikova E, Whitmire KH, Hackerman N, Electrochim. Acta, 53(20), 6024 (2008)
Solmaz R, Corros. Sci., 81, 75 (2014)
Solmaz R, Corros. Sci., 79, 169 (2014)
Xia S, Qiu M, Yu L, Liu F, Zhao H, Corros. Sci., 50, 2021 (2008)
Pearson RG, Inorg. Chem., 27, 734 (1988)
Lukovits I, Klaman E, Zucchi F, Corrosion, 57, 3 (2001)
Tang YM, Yang WZ, Yin XS, Liu Y, Wan R, Wang JT, Mater. Chem. Phys., 116(2-3), 479 (2009)
Awad MK, Mustafa MR, Abo-Elnga MM, J. Mol. Model., 959, 66 (2010)
Hasanov R, Sadikoglu M, Bilgic S, Appl. Surf. Sci., 253(8), 3913 (2007)
Amin MA, Khaled KF, Fadl-Allah SA, Corros. Sci., 55, 140 (2010)

[Referenced By]

[1] Yadav M, Behera D, Sharma U, Corros. Eng. Sci. Technol., 48, 19 (2013)

[2] Vishwanatham S, Sinha PK, Anti-Corros. Methods Mater., 56, 139 (2009)

[3] Bentiss F, Mernari B, Traisnel M, Vezin H, Lagrenee M, Corros. Sci., 53, 487 (2011)

[4] Benali O, Larabi L, Traisnel M, Gengembre L, Harek Y, Appl. Surf. Sci., 253(14), 6130 (2007)

[5] Bentiss F, Lebrini M, Lagrenee M, Corros. Sci., 47, 2915 (2005)

[6] Cruz J, Martinez R, Genesca J, Garcia-Ochoa E, J. Electroanal. Chem., 566(1), 111 (2004)

[7] Khaled KF, Electrochim. Acta, 48(17), 2493 (2003)

[8] Mistry K, Desai KR, Indian J. Chem., 45, 1762 (2006)

[9] Lee C, Yang W, Parr RG, Phys. Rev. B, 37, 785 (1988)

[10] Wang X, Yang H, Wang F, Wang X, Yang H, Wang F, Corros. Sci., 53, 113 (2011)

[11] Li WH, He Q, Zhang ST, Pei CL, Hou BR, J. Appl. Electrochem., 38(3), 289 (2008)

[12] Ramesh S, Rajeswari S, Electrochim. Acta, 49(5), 811 (2004)

[13] Ashassi-Sorkhabi H, Shaabani B, Seifzadeh D, Appl. Surf. Sci., 239(2), 154 (2005)

[14] Behpour SM, Ghoreishi N, Mohammadi N, Soltani M, Corros. Sci., 52, 4046 (2010)

[15] Solmaz R, Kardas G, Culha M, Yazici B, Erbil M, Electrochim. Acta, 53(20), 5941 (2008)

[16] Ozcan M, Dehri I, Erbil M, Appl. Surf. Sci., 236(1-4), 155 (2004)

[17] Lebrini M, Robert F, Lecante A, Roos C, Corros. Sci., 53, 687 (2011)

[18] Dehri I, Ozcan M, Mater. Chem. Phys., 98(2-3), 316 (2006)

[19] Ghareba S, Omanovic S, Electrochim. Acta, 56(11), 3890 (2011)

[20] Machnikova E, Whitmire KH, Hackerman N, Electrochim. Acta, 53(20), 6024 (2008)

[21] Solmaz R, Corros. Sci., 81, 75 (2014)

[22] Solmaz R, Corros. Sci., 79, 169 (2014)

[23] Xia S, Qiu M, Yu L, Liu F, Zhao H, Corros. Sci., 50, 2021 (2008)

[24] Pearson RG, Inorg. Chem., 27, 734 (1988)

[25] Lukovits I, Klaman E, Zucchi F, Corrosion, 57, 3 (2001)

[26] Tang YM, Yang WZ, Yin XS, Liu Y, Wan R, Wang JT, Mater. Chem. Phys., 116(2-3), 479 (2009)

[27] Awad MK, Mustafa MR, Abo-Elnga MM, J. Mol. Model., 959, 66 (2010)

[28] Hasanov R, Sadikoglu M, Bilgic S, Appl. Surf. Sci., 253(8), 3913 (2007)

[29] Amin MA, Khaled KF, Fadl-Allah SA, Corros. Sci., 55, 140 (2010)