Ambient acid leach extraction of Ni-laterites is being heralded as a breakthrough in environmentally conscious mining, however to be successfully exploited they require comprehensive characterisation of their mineralogy and chemistry. This industry-academia collaborative research uses XRD, EPMA and ICPAES techniques to examine the acid leaching characteristics of Turkish Caldag ore. Mineral scale and small column scale leach experiments were carried out with material examined over various lengths of time at ambient conditions. The characterised residues and solution leach inter-relationships and selectivities are compared to bottle roll and heap leach results, demonstrating where true correlations exist and where differences exist as a result of the experimental scale limitations. (C) 2013 Elsevier Ltd. All rights reserved.