In this paper, a mathematical model is developed to predict and assess the evolution of the rheological properties of CPB under the coupled effects of temperature and progress of binder hydration. The model is implemented into the numerical software COMSOL Multiphysics. Then, the prediction ability of the model is assessed by comparing the predicted values with available experimental data from various theological or flowability tests (rheometer, vane shear, and slump tests) on CPB. The model validation test results show that there is good agreement between the predicted and experimentally measured rheological properties of CPB. The simulation results emphasise that the temperature and progress of cement hydration have significant impact on the rheological behaviour and flowability. (C) 2012 Elsevier Ltd. All rights reserved.