화학공학소재연구정보센터
Thin Solid Films, Vol.572, 232-237, 2014
Electron backscatter diffraction characterization of blind hole fillings by electrolytic Cu deposition
Blind hole (BH) filling by electrolytic Cu deposition iswidely used in high density interconnection technology for printed circuit boards. In this study, we investigated Cu deposition behavior in a BH structure using optical microscopy and field-emission scanning electron microscopy in combination with electron backscatter diffraction (EBSD). According to the deposition morphology/rate, the BH filling process was divided into three distinct regimes: (1) the initial deposition regime (t = 20-25 min), (2) the bottom up deposition regime (t = 25-35 min), and (3) the final deposition regime (t = 35-80 min). EBSD analyses showed that the Cu grains were predominantly in the [111]parallel to TD (TD: transverse direction) orientation in the first regime. The [111] Cu grains were predominantly oriented with a takeoff angle of similar to 20 degrees in the bottom up deposition regime. In the final deposition regime, the [111]parallel to RD (RD: rolling direction) and [101]parallel to RD orientations became dominant in the BH fillings. In addition, we characterized the grain boundaries in the Cu deposits with respect to t. The microstructural/crystallographic information presented in this study will improve the understanding of how the electrolytic Cu filling process occurs in a BH structure. (C) 2014 Elsevier B. V. All rights reserved.