Thin Solid Films, Vol.571, 567-572, 2014
Characterization of in-depth cavity distribution after thermal annealing of helium-implanted silicon and gallium nitride
Single-crystalline silicon wafers covered with sacrificial oxide layer and epitaxially grown gallium nitride layers were implanted with high-fluence helium ions (2-6 x 10(16) cm(-2)) at energies of 20-30 keV. Thermal annealings at 650-1000 degrees C, 1 h were performed on the Si samples and rapid thermal annealings at 600-1000 degrees C, 120 s under N-2 were performed on the GaN samples. The as-implanted samples and the near-surface cavity distributions of the annealed samples were investigated with variable angle spectroscopic ellipsometry. In-depth defect profiles and cavity profiles can be best described with multiple independent effective medium sublayers of varying ratio of single-crystal/void. The number of sublayers was chosen to maximize the fit quality without a high parameter cross-correlation. The dependence of the implantation fluence, oxide layer thickness and annealing temperature on the cavity distribution was separately investigated. The ellipsometric fitted distributions were compared and cross-checked with analyses of transmission electron micrographs where the average surface cavity was determined sublayer by sublayer. The in-depth profiles were also compared with simulations of He and vacancy distributions. (C) 2014 Elsevier B.V. All rights reserved.