화학공학소재연구정보센터
Thin Solid Films, Vol.570, 183-188, 2014
Plasma sprayed metal-supported solid oxide fuel cell and stack with nanostructured anodes and diffusion barrier layer
Plasma sprayed LSGM (La0.8Sr0.2Ga0.8Mg0.2O3 - delta) based metal-supported solid oxide fuel cells with nanostructured LDC (Ce0.55La0.45O2 - delta)-Ni anode and LSCM (La0.75Sr0.25Cr0.5Mn0.5O3 - delta) diffusion barrier layer are developed in our institute. The non-sealed single cell measurement configuration is applied to test the performance and the durability of a prepared 10 x 10 cm(2) cell. The tested cell can deliver the power densities of 543, 480, 352 and 214 mW cm(-2) at 0.6 V for the test temperatures of 800, 750, 700 and 650 degrees C respectively. Results obtained from long termdurability test show that this cell with a porous Ni-Fe metal substrate, a porous LSCM diffusion barrier layer, a porous nano-structured LDC-Ni anode layer, a thin dense LDC isolation layer, a dense crack free LSGM electrolyte layer, a porous LSGM-LSCF (La0.6Sr0.4Co0.2Fe0.8O3 - delta) cathode interlayer and a porous LSCF cathode current collecting layer has a degradation rate of similar to 2.2% kh(-1) during the test period of 3700 h at conditions of 700 degrees C and 400 mA cm(-2) current density. The tested 18-cell stack in a sealed configuration shows that it can deliver a power of 606 W at 42.4% fuel utilization, 0.75 V and 800 degrees C. Each cell in the stack has an open circuit voltage larger than 1 V. (C) 2014 Elsevier B. V. All rights reserved.