화학공학소재연구정보센터
Thermochimica Acta, Vol.601, 17-28, 2015
Impact of compressive pressure on the phase stability and transformation behaviour of delta-phase stabilised plutonium alloys
The phase stability of delta-phase stabilised alloys is typically assessed as a function of time by periodically monitoring the specimens using thermal analytical methods. The specimens are subjected to repeat thermal cycling through phase transformations prior to and following conditioning, designed to test the degree of stability of the alloys. This work examines the impact of thermal cycling on the delta-phase stability of Pu-1 at% Ga and Pu-2 at% Ga alloys subjected to compressive stresses. Compressive pressure in the range of 100-300 MPa induced a significant percentage of oil-phase in the Pu-1 at% Ga alloy specimens, whereas no detectable levels of alpha'-phase were recorded in specimens of the Pu-2 at% Ga alloy. However, on thermally cycling the specimens, alpha'-phase was detected in the Pu-2 at% Ga alloy as well. Furthermore, a significant increase in a'-phase was recorded as both alloys were subjected to an increasing number of thermal cycles. The alpha'-phase increase reached a plateau after a given number of cycles for each of the alloys. The transformation of the alpha'-phase back to the delta-phase in specimens of both alloys followed an indirect path via the beta-phase and gamma-phase. Increasing the compressive pressure up to 600 MPa generated higher levels of alpha'-phase in the Pu-1 at% Ga alloy specimens and resulted in significant levels of alpha'-phase being recorded in the Pu-2 at% Ga alloy specimens. The transformation of the alpha'-phase back to the delta-phase appeared to follow an indirect path in the Pu-1 at% Ga alloy. This work shows new evidence that in the Pu-2 at% Ga alloy, the transformation followed both the indirect and direct (alpha'-delta phase) path. Crown Copyright (C) 2014 Published by Elsevier B.V. All rights reserved.