화학공학소재연구정보센터
Solid-State Electronics, Vol.101, 29-32, 2014
Effect of seed layer on surface morphological, structural and optical properties of CdO thin films fabricated by an electrochemical deposition technique
Cadmium oxide (CdO) thin films were grown on Indium Tin Oxide (ITO)-coated glass substrates by an electrochemical deposition technique using CdCL2.6H(2)o (0.02 M) and KCl (0.1 M) solutions at a bath temperature of 70 degrees C and a pH of 6.0. The CdO thin films were produced without seed layers and with seed layers. The surface morphological and structural properties of the CdO thin films were studied by X-ray Diffraction (XRD) and Scanning Electron Microscopy (SEM). The optical properties of the samples were studied by UV-VIS spectroscopy. The X-ray diffraction results revealed that the crystallite sizes of the CdO thin films produced using seed layers at currents of -600 mu A and -800 mu A were 60.9 and 53.0 nm, respectively. However, the crystallite size of the CdO thin film produced without a seed layer at a potential of -0.71 V was 56.9 nm. Furthermore, the energy band gaps of the CdO thin films produced using seed layers at currents of -600 mu A and -800 mu A were 2.140 and 2.283 eV, respectively, while the energy band gap of the CdO thin film produced without a seed layer at a potential of -0.71 V was 2.215 eV. (C) 2014 Elsevier Ltd. All rights reserved.