A sodium ion conducting gel polymer electrolyte based on poly(vinylidene difluoride-co-hexafluoropropylene) porous membrane is reported, which is prepared through a simple phase separation process. It exhibits high safety, good mechanical properties and good electrochemical stability. The gel polymer electrolyte provides the sodium ionic conductivity of 0.60 mS cm(-1) at ambient temperature, while the commercial separator (Celgard 2730) offers only 0.16 mS cm(-1). The temperature dependence of the ionic conductivity from 25 to 75 degrees C is consistent with an Arrhenius-behavior. The ionic transference number of sodium ion (t(Na)(+)) in the gel polymer electrolyte is 0.30, higher than that (0.17) in the commercial separator. This provides a new direction to improve the safety of sodium ion batteries. (C) 2014 Elsevier B.V. All rights reserved.