Carbon-coated lithium iron phosphate (LiFePO4/C) with uniform carbon coating was synthesized by a mechanical activation method. Silicon negative electrode material was obtained in the form of thin films of amorphous silicon on a Cu foil substrate by vertical deposition technique. The electrochemical performance of the full cell, LiFePO4/C-Si, was tested with 1 M LiPF6 in EC/DMC at 0.5 and 1 C-rates. The cell exhibited an initial discharge capacity of 143.9 mAh g(-1) at 0.5 C-rate at room temperature. A reasonably good cycling performance under a high current density of 1 C-rate could be obtained with the full cell. (C) 2014 Elsevier B.V. All rights reserved.