화학공학소재연구정보센터
Solar Energy Materials and Solar Cells, Vol.130, 686-689, 2014
Lifetime improvement after phosphorous diffusion gettering on upgraded metallurgical grade silicon
Wide experimental evidence of the phosphorus diffusion gettering beneficial effect on solar grade silicon is found by measuring electron effective lifetime and interstitial iron concentration in as-grown and post-processed samples from two ingots of upgraded metallurgical grade silicon produced by Ferrosolar. Results after two different P-diffusion processes are compared: P emitter diffusion at 850 C followed by fast cool-down (called "standard process") or followed by slow cool-down (called "extended process"). It is shown that final lifetimes of this low cost material are in the range of those obtained with conventional material. The extended process can be beneficial for wafers with specific initial distribution and concentration of iron, e.g. materials with high concentration of big Fe precipitates, while for other cases the standard process is enough efficient. An analysis based on the comparison of measured lifetime and dissolved iron concentration with theoretical calculations helps to infer the initial iron distribution and concentration, and according to that, choose the more effective type of gettering. (c) 2014 Elsevier B.V. All rights reserved.