The results of equilibrium distribution and transport kinetics of monovalent (Li+, Na+, and Cs+) ions through Nafion-117 ion exchange membrane in presence of polyacrylate anion have been presented. For Na+-Li+ system, equilibrium distributions in the presence and absence of polyacrylate have been found to be the same indicating that the Donnan membrane equilibrium is not affected by the presence of polyacrylate. For the Na+-Cs+ system, a favored transport of Cs+ ion to the polyacrylate compartment has been observed, indicating the binding of Cs+ ion with polyacrylate is stronger than other monovalent ions. This is due to the lower hydration radius of Cs+ ions. The deviation from Donnan membrane equilibrium condition has been used to obtain information about the fraction of counter-ions bound to the polyacrylate. The transport profile in the presence of polyacrylate has also been calculated based on the modified Nernst Planck (NP) approach, taking into account the fraction of counter-ions bound to the polyacrylate ion. The Donnan relation has been used to obtain the concentration of ions at the solution/membrane interface. The self-diffusion coefficients of ions and membrane ion exchange capacity have been given as input parameters in the calculations. The calculated time profile has been found to agree well with the experimental time profile.