Acetylenic monomers containing salicylidene Schiff-base groups (1a and 1b) as well as Schiff-base and hydroxy groups (1c) were synthesized and polymerized with [(nbd)RhCl](2)/Et3N catalyst to afford the corresponding polymers 2a-c with high molecular weights (M-n = 2.6-7.2 x 10(5)) in high yields (75-97%). Polarimetric, circular dichroism (CD), and UV-vis spectroscopic analyses indicated that the polymers formed helical structures with a predominantly one-handed screw sense. The addition of metal ions to salicylidene Schiff-base-containing polymers 2a and 2b produced insoluble polymer/metal complexes through ionic cross-linking as a result of salicylaldimine-metal ion complexation. Polymers 2b and 2c underwent a helix-coil transition upon the addition of HSO4-, whereas these polymers did not exhibit responsiveness to other anions, such as F-, Cl-, and Br-. (C) 2015 Elsevier B.V. All rights reserved.