Cyanidation is one of the most common methods for the extraction of precious metals. In this process, effluents frequently contain relatively high concentrations of copper, which may react with cyanide to form cuprocyanide complexes adversely affecting the process. In this preliminary work, the use of solvent extraction to remove the copper-cyanide species from a synthetic solution similar to that of gold mill effluents was studied in order to permit the recycling of the solution into the process. For the extraction of these anions, the quaternary ammonium salts Quartamin TPR, Adogen 464 and Aliquat 336 were studied as extractants. The experimental results showed that for a synthetic solution of 710 mg/L copper and 1100 mg/L cyanide, it is possible to obtain a copper extraction of 99% when using 0.033 mol/L of the extractant Adogen 464 (organic/aqueous volume ratio (O/A) = 1) in the range of pH of 9-11. Up to 99% of the copper can be stripped from the organic solution after three contact times (5 min each) with 50 mL of sodium hydroxide 0.5 M (O/A = 1). (C) 2010 Elsevier Ltd. All rights reserved.