Base metals such as copper, nickel and cobalt ave usually recovered by the employment of a selective acid leach followed by electrowinning and/or precipitation techniques. The selective dissolution usually involves a 3-stage sulphuric acid leach incorporating recycling and impurity removal. in this study an alternative process, namely a total leach followed by the selective recovery of the base metals by ion exchange resin, is investigated. The first phase of the project focused on the selective removal of copper from an electrolyte solution employing a sodium based synthetic resin. It has been found that copper could selectively be recovered but that conventional isotherms do not describe equilibrium conditions accurately in all cases. This is explained by the lack of interdependency of equilibrium solution concentrations in the relationships. However, copper equilibrium is adequately described by a single solute isotherm, manifesting the insensitivity of the resin selected towards the level of nickel and cobalt in solution. Furthermore, nickel equilibrium conditions were well explained by a Fritz and Schleunder-type multi-component isotherm.