Materials Research Bulletin, Vol.63, 112-115, 2015
The fabrication of foam-like 3D mesoporous NiO-Ni as anode for high performance Li-ion batteries
Foam-like three dimensional mesoporous NiO on Ni foam was fabricated via facile hydrothermal etching and subsequent annealing treatment. The porous NiO consists of a large number of nanosheets with mean thickness about 50 nm, among which a large number of mesoscopic pores with size ranges from 100 nm to 1 mu m distribute. The electrochemical performance of the as-prepared NiO-Ni as anode for lithium ion battery was studied by conventional charge/discharge test, which shows excellent cycle stability and rate capability. It exhibits initial discharge and charge capacities of 979 and 707 mA h g(-1) at a charge/discharge rate of 0.7 C, which maintain of 747 and 738 mA h g(-1) after 100 cycles. Even after 60 cycles at various rates from 0.06 to 14 C, the 10th discharge and charge capacities of the NiO-Ni electrode can revert to 699 and 683 mA h g(-1) when lowering the charge/discharge rate to 0.06 C. (C) 2014 Elsevier Ltd. All rights reserved.