화학공학소재연구정보센터
Materials Chemistry and Physics, Vol.152, 62-68, 2015
Stable quasi-solid-state dye-sensitized solar cell using ionic gel electrolyte with low molecular mass organogelator
Long-term stability is essential for the application and commercialization of dye-sensitized solar cells (DSCs). A quasi-solid-state DSC (QS-DSC) with excellent long-term stability is fabricated using ionic gel electrolyte (ICE) with N,N'-methylenebisdodecanamide as low molecular mass organogelator (LMOG). The gel to solution transition temperature (T-gel) of this ICE is 127 degrees C, well above the working temperature of the device, which contributes to the thermal properties of the IGE and the device. The electrochemical properties of the ICE and the kinetic processes of electron transport and recombination of the QS-DSC are investigated by means of electrochemical impedance spectroscopy (EIS) and controlled intensity modulated photocurrent/photovoltage spectroscopy (IMPS/IMVS). Due to the obstructed diffusion of redox species caused by the network of IGE, the electron recombination at the TiO2 photoelectrode/electrolyte interface in the QS-DSC is accelerated. More importantly, compared with the ionic liquid electrolyte (ILE) based DSC, the QS-DSC based on the ICE exhibits excellent thermal and light-soaking stabilities during the accelerated aging tests for 1000 h. Especially, there is almost no degradation in the short-circuit current density (J(sc)) in the ICE based QS-DSC, while the J(sc) of the ILE based DSC decreased to 85-94% of their initial values. (C) 2014 Elsevier B.V. All rights reserved.