The 3-dimensional hierarchical TiO2 particles of micro-sized diameter were synthesized through modified sol gel process with polyethylene glycol (PEG) as a structure-controlling agent. The anatase crystal structure was obtained after calcination at 450 degrees C. The size and specific surface area of particles were 1.0-1.8 mu m and 96.85 m(2) g(-1), respectively. The specific surface area of the TiO2 particles corresponded to that of the spherical nanoparticles with average size of 15.9 nm. Although the size of synthesized TiO2 was micro-scale, they had the specific surface area similar to that of nano-scale particles due to the effect of PEG on the formation of particles. Subsequently, the surface modification with various concentration of ammonia solution was carried out for the preparation of hydroxyl-rich TiO2 particles at surfaces. As the concentration of ammonia solution was increased, the amount of chemically adsorbed hydroxyl groups on the TiO2 surface was increased. As an application of prepared TiO2 for water treatment, their catalytic performances for the degradation of methylene blue (MB) were examined by using UV-Vis spectrophotometer with the assistance of UV lamp. After hydroxylation treatment, the micro-sized TiO2 particles showed the higher performance of MB degradation than that of nano-sized P25 particles because of their large specific surface area and hydroxyl-rich surface. (C) 2014 Elsevier B.V. All rights reserved.