화학공학소재연구정보센터
Journal of the Electrochemical Society, Vol.161, No.14, F1489-F1501, 2014
Development of Highly Active and Durable Hybrid Cathode Catalysts for Polymer Electrolyte Membrane Fuel Cells
Carbon composite catalyst (CCC) and activated carbon composite catalyst (A-CCC), both containing active catalytic sites for oxygen reduction reaction (ORR), were synthesized and used as supports to develop hybrid cathode catalysts (HCCs). HCCs are a combination of CCC or A-CCC supports and Pt or Co-doped Pt catalysts. Uniform Pt deposition on these supports was accomplished through surface modification and modified polyol processes. The Co-doped Pt was synthesized at 800 degrees C in the presence of polyaniline protective coating. The HCCs, namely Pt/A-CCC, Co-doped Pt/CCC, and L-Co-doped Pt/CCC catalysts showed peak power densities of 944, 857, and 1050 mW cm(-2), respectively, which are much higher than the commercial Pt/C (746 mW cm(-2)). Furthermore, the Pt/C showed very high power density loss (63%) when compared to HCCs (16-26% loss) after 30,000 potential cycles (0.6-1.0 V). The Pt/A-CCC catalyst showed excellent support stability when subjected to potential holding at 1.2 V for 400 h (27 mV loss at 800 mA cm(-2)) and 5,000 potential cycles between 1.0 and 1.5 V (25 mV loss at 1500 mA cm-2) which are less than that of 2017 US DOE targets (<= 30 mV loss). The durability studies indicated that the HCCs are promising cathode catalysts for transportation applications. (C) 2014 The Electrochemical Society. All rights reserved.