화학공학소재연구정보센터
Journal of Crystal Growth, Vol.403, 72-76, 2014
Optical and electrical properties of dislocations in plastically deformed GaN
Optical and electrical properties of fresh dislocations in GaN bulk crystals deformed plastically at elevated temperatures were reviewed. A dislocation band model was proposed. The fresh dislocations of (a/3) [1 (2) over bar 10]-type edge dislocations on the (10 (1) over bar0) prismatic plane induced several photoluminescence peaks at around 1.8, 1.9 and 2.4 eV, which implies the formation of radiative recombination centers of the dislocations. Simultaneously, near-band-edge (3.48 eV) photoluminescence intensity decreased remarkably for a high-density of non-radiative recombination centers originating in deformation-induced abundant Ga-vacancy related clusters. The intensity variation of yellow luminescence with plastic deformation and subsequent annealing did not relate to the native property of dislocations. Variation of optical absorption dependent on the strain in plastically deformed GaN was understood in a model of the Franz-Keldysh effect by the electric fields associated with charged dislocations (similar to 5.8 e/nm). Scanning spreading resistance microscopic images showed many spots with high conductivity around the induced dislocations, showing electrical conduction along dislocations according to the Frenkel-Poole mechanism. (C) 2014 Elsevier B.V. All rights reserved.