International Journal of Hydrogen Energy, Vol.39, No.33, 19039-19050, 2014
Nd1.8Sr0.2NiO4_(delta):Ce0.9Gd0.1O2-delta composite cathode for intermediate temperature solid oxide fuel cells
The (100-x)Nd1.8Sr0.2NiO4-delta:(x)Ce0.9Gd0.1O2-delta (x = 00, 10, 20, 30, 40 and 50 vol%) composites are obtained by ball milling requisite mixture at 200 rotations per minute for 2 h under acetone followed by sintering at 1000 degrees C for 4 h. The increase in concentration of Ce0.9Gd0.1O2-delta in composite reduces the crystallite size of host Nd1.8Sr0.2NiO4-delta from 378 +/- 0.7 to 210 +/- 0.8 nm. The dc (electronic) conductivity of composite decreases moderately with an increase in Ce0.9Gd0.1O2-delta, content in composite up to 30 vol%, and it decreases abruptly, thereafter at x > 30. A minimum polarization resistance value of 0.24 Omega cm(2) (at 700 degrees C) is obtained for a (70)Nd1.8Sr0.2NiO4-delta:(30)Ce0.9Gd0.1O2-delta composite cathode, and this value is attributed to the optimal dispersion of Ce0.9Gd0.1O2-delta into Nd1.8Sr0.2CuO4-delta matrix. The oxygen partial pressure dependent polarization resistance study suggests that the charge transfer and the non-charge transfer oxygen adsorption-desorption along with diffusion are the major rate limiting steps of overall oxygen reduction reaction process. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
Keywords:Intermediate temperature solid;oxide fuel cell;Electrochemical impedance spectroscopy;Composite cathode;dc Conductivity