The utilization of solar energy for the conversion of water to hydrogen and oxygen has been considered to be an efficient strategy to solve crisis of energy and environment. Here, we report the synthesis of reduced graphene oxide-TiO2 nanoparticle composite system through the photocatalytic reduction of graphite oxide using TiO2 nanoparticles. Photoelectrochemical characterizations and hydrogen evolution measurements of these nanocomposites reveal that the presence of graphene enhances the photocurrent density and hydrogen generation rate. The optimum photocurrent density and hydrogen generation rate has been found to be 3.4 mA cm(-2) and 127.5 mu mole cm(-2)h(-1) in 0.5 M Na2SO4 electrolyte solution under 1.5AM solar irradiance of white light with illumination intensity of 100 mW cm(-2). In graphene TiO2 nanocomposite, photogenerated electrons in TiO2 are scavenged by graphene sheets and percolate to counter electrode to reduce H+ to molecular hydrogen thus increasing the performance of water-splitting reaction. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.