La0.6Ce0.4Ni3.45Co0.75Mn0.7Al0.1 hydrogen storage alloy has been prepared and its electro-chemical characteristics and gas hydrogen absorption/desorption properties have been investigated at different temperatures. X-ray diffraction results indicated that the alloy consists of a single phase with CaCu5-type structure. It is found that the investigated alloy shows good cycle performance and high-rate discharge ability, which display its promising use in the high-power type Ni-MN battery. The exchange current density and the diffusion coefficient of hydrogen in the bulky electrode increase with increasing temperature, indicating that increasing temperature is beneficial to charge-transfer reaction and hydrogen diffusion. However, the maximum discharge capacity, the charge retention and the cycling stability degrade with the increase of the temperature. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.