Inorganic Chemistry, Vol.53, No.17, 8851-8853, 2014
Partial Hydrogenation of a Tetranuclear Titanium Nitrido Complex with Ammonia Borane
The treatment of [{Ti(eta(5)-C5Me5)}(4)(mu(3)-N)(4)] with NH3BH3 leads to the paramagnetic imidonitrido complex [{Ti(eta(5)-C5Me5)}(4)(mu(3)-N)(3)(mu(3)-NH)], which can also be obtained by stepwise proton and electron transfer with HOTf and [K(C5Me5)].