Journal of Electroanalytical Chemistry, Vol.414, No.2, 247-251, 1996
Channel Microband Electrodes - A Complete Working Surface for Potential Step Transients
The strongly implicit procedure is used to simulate the chronoamperometric transient resulting from a potential step at a channel microband electrode. A working surface is presented which permits the analysis of data recorded at any flow rate, including cases where axial diffusion effects are significant, and for cells of arbitrary geometry.
Keywords:STRONGLY IMPLICIT PROCEDURE;MASS TRANSPORT CONDITIONS;MICROJET ELECTRODE;TRANSFER RATES;VOLTAMMETRY;KINETICS;MICROELECTRODES