Carbon nanostructures (CNSs) in the form of fibers and spheres have been successfully grown on 3 dimensional (3D) macroscopic silicon carbide (SiC) foams with the aid of mesoporous silica-films as interfacial layer via ethylene decomposition on nickel and iron as growth catalysts using chemical vapor deposition (CVD). The effect of growth temperature from 600 to 900 degrees C on morphology, diameter and specific surface area of as-grown CNSs was studied. The as-grown CNSs were characterized by field emission scanning electron microscope (FE-SEM) and transmission electron microscope (TEM) to examine the morphology, diameter, microstructure and defect. Crystallinity and degree of graphitization were determined by X-ray diffraction and Raman spectrometer. Textural properties such as specific surface area, pore size and pore volume were measured by nitrogen gas adsorption-desorption. Uniform distribution of CNSs on 3D SiC-foam was obtained at 700 degrees C for short synthesis time (30 min), as well as high surface area of above 100 m(2)/g. Degree of graphitization of CNSs grown on modified SiC substrates by using Ni as growth catalyst was higher than the one with the Fe-growth catalyst. (C) 2014 Elsevier B.V. All rights reserved.