포페이트계열 형광체의 합성 및 광특성 평가

노세철; 김유혁; Seh-Chul Noh; Youhyuk Kim

Korean Journal of Materials Research, Vol.12, No.1, 21-26, January, 2002

DOI10.3740/MRSK.2002.12.1.021 Export Citation

포페이트계열 형광체의 합성 및 광특성 평가

Preparation and Luminescent Characteristics of Phosphate-Based Phosphors

노세철, 김유혁^†

단국대학교 첨단 과학부

Seh-Chul Noh, and Youhyuk Kim^†

Department of Chemistry, School of Advanced Science, Dankook University, Cheonon, Chungnam 330-714, Korea

E-mail:

In order to search new phosphors for plasma display panel(PDP), phosphate hosts which has a host excitation band at around 150nm were prepared and their luminescent properties were investigated. In the preparation of YPO 4 :Euand(Y,Gd)PO 4 :Eu phosphors, the effect of oxide and oxalate starting materials on prepared phosphors were compared in terms of relative emission intensities and particle characteristics. The results showed that oxalate starting materials gave better performance in emission intensities and smaller size and more round shape phosphors which would be more applicable for high resolution display. Additionally, Gd, V, Nb and Ta ions were doped to YPO 4 :Eu and the luminescent properties of the resulant solid solutions were investigated to find efficient sensitizer. Among these ions, Gd, V and Nb ions increased the emission intensities of parent phosphor to around 10%. While Nb ion gave the best result in emission intensities, CIE color coordinate were improved by doping V ion into YPO 4 :Eu phosphor to give x=0.6523, y=0.3406 compared to commercial sample.

Keywords:chemical synthesis;oxalate;phosphate;PDP(Plasma Display Panel);Phosphors;Luminescence

[References]

Lee YW, in Proceedings of the 18th International Display Research Conference (Seoul, Korea, Sept. 1998) p. 5 (1998)
Matsumoto S, Electronic Display Devices, John Wiley & Sons, New York (1984) (1984)
Yoshimura F, Yamakaya M, in Proceedings of the Third International Display Workshops (Kobe, Japan, Nov. 1996) 2, p.77 (1996)
Nakazawa E, Shiga F, Luminescence J, 15, 255 (1997) (1997)
Kim C, Bae H, Byun J, Hong K, J. korean Chem Soc, 42, 588 (1998)
Sordelet D, Akinc M, J. Colloid Interface Sci., 122, 47 (1988)
Cho SH, Kwon SH, Yoo JS, Oh CW, Lee JD, Hong KJ, Kwon SJ, J. Electrochem. Soc., 147(8), 3143 (2000)
Lin J, Sanger DU, Mennig M, Barner K, Mater. Sci. Eng., 864, 73 (1999)
Lu SW, Copeland T, Lee BI, Tong W, Wagner BK, Park W, Zhang F, J. Phys. Chem. Solid, 62, 777 (2001)
Dexter DL, Schulman JH, J. Chem. Phys., 22, 1063 (1954)
Oshio S, Kitamura K, Shigeta T, Horii S, Matsuoka T, Tanaka S, Kobayashi H, J. Electrochem. Soc., 146(1), 392 (1999)
Kang YC, Park SB, Lenggoro IW, Okuyama K, J. Electrochem. Soc., 146(7), 2744 (1999)
Blasse G, Bril A, Philips Technical Review, 31, 304 (1970)
Blasse G, Grabmaier BC, Luminescent Materials p. 41 Springer-Verlag, (1994) (1994)
Shionoya S, Yen WM, Phosphor Handbook CRC Press, p.261 (1998) (1998)
Rambabu U, Buddhuda S, Optical Materials, 17, 401 (2001)
Fukuzawa T, Tanimizu S, J. Luminescence, 16, 447 (1978)
Ropp RC, J. Electrochem. Soc., 112, 181 (1965)
Shin Y, Do Y, Kim Y, Bull. Kor. Chem. Soc., 18, 1112 (1997)

[1] Lee YW, in Proceedings of the 18th International Display Research Conference (Seoul, Korea, Sept. 1998) p. 5 (1998)

[2] Matsumoto S, Electronic Display Devices, John Wiley & Sons, New York (1984) (1984)

[3] Yoshimura F, Yamakaya M, in Proceedings of the Third International Display Workshops (Kobe, Japan, Nov. 1996) 2, p.77 (1996)

[4] Nakazawa E, Shiga F, Luminescence J, 15, 255 (1997) (1997)

[5] Kim C, Bae H, Byun J, Hong K, J. korean Chem Soc, 42, 588 (1998)

[6] Sordelet D, Akinc M, J. Colloid Interface Sci., 122, 47 (1988)

[7] Cho SH, Kwon SH, Yoo JS, Oh CW, Lee JD, Hong KJ, Kwon SJ, J. Electrochem. Soc., 147(8), 3143 (2000)

[8] Lin J, Sanger DU, Mennig M, Barner K, Mater. Sci. Eng., 864, 73 (1999)

[9] Lu SW, Copeland T, Lee BI, Tong W, Wagner BK, Park W, Zhang F, J. Phys. Chem. Solid, 62, 777 (2001)

[10] Dexter DL, Schulman JH, J. Chem. Phys., 22, 1063 (1954)

[11] Oshio S, Kitamura K, Shigeta T, Horii S, Matsuoka T, Tanaka S, Kobayashi H, J. Electrochem. Soc., 146(1), 392 (1999)

[12] Kang YC, Park SB, Lenggoro IW, Okuyama K, J. Electrochem. Soc., 146(7), 2744 (1999)

[13] Blasse G, Bril A, Philips Technical Review, 31, 304 (1970)

[14] Blasse G, Grabmaier BC, Luminescent Materials p. 41 Springer-Verlag, (1994) (1994)

[15] Shionoya S, Yen WM, Phosphor Handbook CRC Press, p.261 (1998) (1998)

[16] Rambabu U, Buddhuda S, Optical Materials, 17, 401 (2001)

[17] Fukuzawa T, Tanimizu S, J. Luminescence, 16, 447 (1978)

[18] Ropp RC, J. Electrochem. Soc., 112, 181 (1965)

[19] Shin Y, Do Y, Kim Y, Bull. Kor. Chem. Soc., 18, 1112 (1997)