Boron doped diamond (BDD) has remarkable physical and chemical properties, that makes it an attractive material for electrochemical applications. In this study, deposition process of BDD on porous carbon foam electrodes was performed by HFCVD method. After depositions, the substrates were not homogenously covered by the BDD thin film only. Depending on the deposition temperature, foam porosity and distance from heated filaments, different carbon nanomaterials were synthesized. The boron doped diamond, graphite nanosheets, carbon nanowalls and its composites occurred on the foams outer and inner surfaces. Two new observed types of carbon structures, the carbon nanowalls - boron doped diamond composite and graphite nanotips are analyzed and described. Analyses were made by SEM and Raman spectroscopy. The influence of deposition conditions on the growth process is discussed. (C) 2014 Elsevier B.V. All rights reserved.