티타늄 기판 위에 강유전성 BaTiO 3 박막 형성과 분극처리에 의한 Eagle's MEM 용액에서의 Calcium Phosphate 생성

이용렬; 정영화; 황규석; 송호준; 박영준; Yong-Ryeol Lee; Young-Hwa Jeong; Kyu-Seog Hwang; Ho-Jun Song; Yeong-Joon Park

Korean Journal of Materials Research, Vol.12, No.7, 560-567, July, 2002

DOI10.3740/MRSK.2002.12.7.560 Export Citation

티타늄 기판 위에 강유전성 BaTiO 3 박막 형성과 분극처리에 의한 Eagle's MEM 용액에서의 Calcium Phosphate 생성

Fabrication of Ferroelectric BaTiO 3 Thin Film on Ti Substrate and Formation of Calcium Phosphate in Eagle's MEM Solution

이용렬, 정영화, 황규석¹, 송호준², 박영준^†

전남대학교 치과대학 치과재료학교실 및 치과재료연구소
¹남부대학교 자동차기계공학부
²한국기초과학연구원

Yong-Ryeol Lee, Young-Hwa Jeong, Kyu-Seog Hwang¹, Ho-Jun Song², and Yeong-Joon Park^†

Dept. of Dental Materials and Dental Materials Research Institute, College of Dentistry, Chonnam National University, Gwangju 501-840, Korea
¹School of Automotive Mechanical Engineering, Nambu University, Gwangju 506-302, Korea
²Korea Basic Science Institute, Gwangju 500-757, Korea

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itanium (Ti) is a bioinert material and has lower elastic coefficient and better strength/volume property than other metals. Ferroelectric materials show alignment of positive and negative charges by poling treatment. This study was purposed to develop a new implant system by combining the advantages of Ti and ferroelectric property of BaTiO 3 (BTO). It was performed with the assumption that the Ca 2+ ions would be easily attracted on negatively charged surface and the attracted cation might behave as nuclei for bone-like crystal growth in biological solutions. A ferroelectric BTO thin film on Ti was fabricated and the effect of poling treatment on the improvement of calcium phosphate (Ca-P) formation in biological solutions was evaluated. After immersion in Eagle's minimum essential media (MEM) solution, NaCl was formed on Ti, and Ca-P layer containing NaCl was formed on Ti-O. Weak and sparse Ca-P layers were formed on BTO, while thick, homogeneous, and dense Ca-P layer was formed on negatively polarized BTO (N-BTO), which was confirmed by FE-SEM and EDX. In summary, these results demonstrate that poling the ferroelectric BTO surface negatively is effective for the formation of Ca-P layer in MEM solution, and that N-BTO coating on Ti could be used as a possible alternative method for enhancing the osseointegration of the implants.

Keywords:ferroelectric;barium titanate;thin- film;calcium phosphate;poling;osseointegration

[References]

Kaiculis S, Mattogno G, Napoli A, Bernporad E, Ferrari F, Montenero A, Gnappi G, J. Electron Spectrosc. Relat. Phenom., 95, 61 (1998)
Ban S, Matsuo K, Mizutani N, Hasegawa J, Dent. Mater. J., 18(3), 259 (1999)
Montenero A, Gnappi G, Ferrari F, Cesari M, Salvioli E, Mattogno L, Kaciulis S, Fini M, J. Mater. Sci., 35(11), 2791 (2000)
Jaffe B, Cook WR, Jaffe H, Piezoelectric Ceramics, p.53, Academic Press, London and New York, (1971) (1971)
Moulson AJ, Herbert JM, Electroceramics : materials, properties, applications, p.68, Chapman and Hall, London, (1990) (1990)
Matsuoka, Hoshino K, Ono K, J. Appl, Phys., 76(3), 1768 (1994)
Wills LA, Wessels BW, Richeson DS, Marks TJ, Appl. Phys. Lett., 60(1), 41 (1992)
Kaiser DL, Vaudin MD, Rotter LD, Wang ZL, Cline JP, Hwang CS, Marinenko RB, Gillen JG, Appl. Phys. Lett., 66(21), 2801 (1995)
Nashimoto K, Fork DK, Geballe TH, Appl. Phys. Lett., 60(10), 1199 (1992)
Srikant V, Tarsa EJ, Clarke DR, Speck JS, J. Appl. Phys., 77(4), 1517 (1995)
Kumazawa H, Masuda K, Thin Solid Films, 353(1-2), 144 (1999)
Yasuda I, Noguchi K, Sata T, J. Bone. Joint. Surg., 37-A(6), 1292 (1955)
Yamashita K, Oikawa N, Urnegaki T, Chem. Mater., 8, 2697 (1996)
Park YJ, Lee YR, Song JE, Hwang KS, Ong JL, Rawls HR, J. Dent. Res., 80(81), 569 (2001)
Salman NN, Park JB, Biomaterials, 1, 209 (1980)
Friedenberg ZB, Zemsky LM, Pollis RP, Brighton CT, J. Bone. Joint. Surg., 56-A, 1023 (1974)
Lavine LS, Lustrin I, Shamos MH, Rinaldi RA, Liboff AR, Science, 175, 1118 (1972)
Shimizu T, Zerwekh JE, Videruan T, Gill K, Mooney V, Holmes RE, Hagler HK, J. Orthop, Res., 6, 248 (1988)
Bassett CAL, Pawluk RJ, Pilla AA, Science, 184, 575 (1974)
Spadaro JA, Bioelectromagnetics, 18, 193 (1997)
Okazaki K, Ceramic engineering for dielectrics, p.171, Gakken -sha Publishing Co, Tokyo, (1992) (1992)
Park YJ, Shin MS, Yang HS, Ong JL, Rawls HR, Proceedings of Southern Biomedical Engineering Conference, 17, 124 (1998)
Hayashi T, Oji N, Maiwa H, Jpn. J. Appl. Phys., 33, 5277 (1994)
Okamura S, Kakimi A, Ysukamoto T, J. Ceram. Soc. Jpn., 103(2), 202 (1995)
Mustafa K, Wennerberg A, Wroblewski J, Hultenby K, Lopez BS, Arvidson K, Clin. Oral. Implan. Res., 12(5), 515 (2001)
Deligianni DD, Katsaka N, Ladas S, Sotiropoulou D, Amedee J, Missirlis YF, Biomaterials, 22, 1241 (2001)
Schwartz Z, Kieswetter K, Dean DD, Boyan BD, J. Periodontal. Res., 32(1), 166 (1997)
Hamanaka H, in Proceedings of the Fifth International Symposium on Titanium in Dentistry (Chiba, Japan, June 2001), Society for Titanium Alloys in Dentistry, p. 1 (2001)
Schwartz Z, Lohmann CH, Sisk M, Cochran DL, Sylvia VL, Simpson J, Dean DD, Boyan BD, Biomaterials, 22(&), 731 (2001)
Dijk KV, Schadken HG, Wolke JCG, Maree CHM, Habraken FHPM, Verhoeven J, Jansen JA, J. Biomed. Mater. Res., 29, 269 (1995)

[1] Kaiculis S, Mattogno G, Napoli A, Bernporad E, Ferrari F, Montenero A, Gnappi G, J. Electron Spectrosc. Relat. Phenom., 95, 61 (1998)

[2] Ban S, Matsuo K, Mizutani N, Hasegawa J, Dent. Mater. J., 18(3), 259 (1999)

[3] Montenero A, Gnappi G, Ferrari F, Cesari M, Salvioli E, Mattogno L, Kaciulis S, Fini M, J. Mater. Sci., 35(11), 2791 (2000)

[4] Jaffe B, Cook WR, Jaffe H, Piezoelectric Ceramics, p.53, Academic Press, London and New York, (1971) (1971)

[5] Moulson AJ, Herbert JM, Electroceramics : materials, properties, applications, p.68, Chapman and Hall, London, (1990) (1990)

[6] Matsuoka, Hoshino K, Ono K, J. Appl, Phys., 76(3), 1768 (1994)

[7] Wills LA, Wessels BW, Richeson DS, Marks TJ, Appl. Phys. Lett., 60(1), 41 (1992)

[8] Kaiser DL, Vaudin MD, Rotter LD, Wang ZL, Cline JP, Hwang CS, Marinenko RB, Gillen JG, Appl. Phys. Lett., 66(21), 2801 (1995)

[9] Nashimoto K, Fork DK, Geballe TH, Appl. Phys. Lett., 60(10), 1199 (1992)

[10] Srikant V, Tarsa EJ, Clarke DR, Speck JS, J. Appl. Phys., 77(4), 1517 (1995)

[11] Kumazawa H, Masuda K, Thin Solid Films, 353(1-2), 144 (1999)

[12] Yasuda I, Noguchi K, Sata T, J. Bone. Joint. Surg., 37-A(6), 1292 (1955)

[13] Yamashita K, Oikawa N, Urnegaki T, Chem. Mater., 8, 2697 (1996)

[14] Park YJ, Lee YR, Song JE, Hwang KS, Ong JL, Rawls HR, J. Dent. Res., 80(81), 569 (2001)

[15] Salman NN, Park JB, Biomaterials, 1, 209 (1980)

[16] Friedenberg ZB, Zemsky LM, Pollis RP, Brighton CT, J. Bone. Joint. Surg., 56-A, 1023 (1974)

[17] Lavine LS, Lustrin I, Shamos MH, Rinaldi RA, Liboff AR, Science, 175, 1118 (1972)

[18] Shimizu T, Zerwekh JE, Videruan T, Gill K, Mooney V, Holmes RE, Hagler HK, J. Orthop, Res., 6, 248 (1988)

[19] Bassett CAL, Pawluk RJ, Pilla AA, Science, 184, 575 (1974)

[20] Spadaro JA, Bioelectromagnetics, 18, 193 (1997)

[21] Okazaki K, Ceramic engineering for dielectrics, p.171, Gakken -sha Publishing Co, Tokyo, (1992) (1992)

[22] Park YJ, Shin MS, Yang HS, Ong JL, Rawls HR, Proceedings of Southern Biomedical Engineering Conference, 17, 124 (1998)

[23] Hayashi T, Oji N, Maiwa H, Jpn. J. Appl. Phys., 33, 5277 (1994)

[24] Okamura S, Kakimi A, Ysukamoto T, J. Ceram. Soc. Jpn., 103(2), 202 (1995)

[25] Mustafa K, Wennerberg A, Wroblewski J, Hultenby K, Lopez BS, Arvidson K, Clin. Oral. Implan. Res., 12(5), 515 (2001)

[26] Deligianni DD, Katsaka N, Ladas S, Sotiropoulou D, Amedee J, Missirlis YF, Biomaterials, 22, 1241 (2001)

[27] Schwartz Z, Kieswetter K, Dean DD, Boyan BD, J. Periodontal. Res., 32(1), 166 (1997)

[28] Hamanaka H, in Proceedings of the Fifth International Symposium on Titanium in Dentistry (Chiba, Japan, June 2001), Society for Titanium Alloys in Dentistry, p. 1 (2001)

[29] Schwartz Z, Lohmann CH, Sisk M, Cochran DL, Sylvia VL, Simpson J, Dean DD, Boyan BD, Biomaterials, 22(&), 731 (2001)

[30] Dijk KV, Schadken HG, Wolke JCG, Maree CHM, Habraken FHPM, Verhoeven J, Jansen JA, J. Biomed. Mater. Res., 29, 269 (1995)