양이온 성분이 수산화철 형성에 미치는 영향 조사

오세진; 이재영; 권순주; 유장용; 주웅용; Sei-Jin Oh; Jae-Yong Lee; Soon-Ju Kwon; Jang-Yong Yoo; Wung-Yong Choo

Korean Journal of Materials Research, Vol.12, No.10, 796-802, October, 2002

DOI10.3740/MRSK.2002.12.10.796 Export Citation

양이온 성분이 수산화철 형성에 미치는 영향 조사

Studying the Effect of Cation to the Formation of Iron Oxyhydroxide

오세진^†, 이재영¹, 권순주², 유장용³, 주웅용³

주성대학 음향공학과
¹포항산업과학연구원 자원활용팀
²포항공과대학교 재료공학과
³포항제철기술연구소 후판연구팀

Sei-Jin Oh^†, Jae-Yong Lee¹, Soon-Ju Kwon², Jang-Yong Yoo³, and Wung-Yong Choo³

Department of Acoustical Eng., Jusung College, Korea
¹Resource Recycling Team, Research Institute of Industrial Science and Science, Korea
²Department of Materials Science and Engineering, Pohang University of Science and Technology, Korea
³Plate, Rod and Welding Research Team, Technical Research Laboratory, Pohang Iron and Steal Co., Ltd., Korea

E-mail:

fect of nine different cations to the formation of iron oxyhydroxide was studied using Mossbauer spectroscopy, XRD and BET. The Redox Potential and pH were measured for the determination of the internal reaction rate, as well. The phases of iron oxyhydroxide could not be the same with each other, due to the present of different cations in solution. Although the oxyhydroxide compound were composed of the same phases, the fraction of each phase was different from each other. The internal reaction rate was varied by the substitution of cation. It could be a cause of the different phase and particle size of oxyhydroxide compound.

Keywords:iron oxyhydroxide;cation;Redox Potential;pH;internal reaction rate

[References]

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Shastry CR, Friel JJ,Townsend HE, ASTM STP 965 (Philadelphia, PA ASTM, 1988) 5 (1988)
Townsend HE, Zoccola ZC, ASTM 767 (Philadelphia, PA ASTM, 1988) 45 (1988)
Oh SJ, Ph.D Thesis, Old Dominion University, Department of Physics, 1997 (1997)
Yun TS, J. Korean Institute of Metals and Materials, 15(2), 8 (1977)
Dillon CP, Corrosion Control in the Chemical Process Industries (Materials Technology Institute of the Chemical Process Industries, Inc., 1994) (1994)
Yamashita M, Miyuki H, Nagano H, Misawa T, Corro. Eng., 4, 43 (1994)
Misawa T, Asami K, Hashimoto K, Shimodaira S, Corr. Sci., 14, 279 (1974)
Suzuki I, Hisamatsu Y, J. Electrochem. Soc., 127(10), 2210 (1980)
Stratmann M, Bohnenkamp K, Ramchandran T, Corr. Sci., 27(9), 905 (1987)
Kihira H, Ito S, Murata T, Corr. Sci., 31, 383 (1990)
Nishikayta A, Yamashita Y, Katayama H, Tsuru T, Usami A, Tanabe K, Mabuchi, Corr. Sci., 37, 2059 (1995)
Yamashita M, Misawa T, Proc. 3rd NACE Am. Reging Corr. Cong. (1998)
Miyuki H, Zairyo-to-Kankyo, 47, 186 (1998)
Oh SJ, Kwon SJ, Cook DC, Townsend HE, Hyp. Int., C4, 37 (1999)
Balasubramanian R, Cook DC, Perez T, Reyes J, Hyp. Int., C4, 37 (1999)
Yamashita M, Nagano H, Misawa T, Townsend HE, ISIJ Int., 38, 285 (1998)
Jackson E, Hydrometallurgical Extraction and Reclamation, (John Willey & Sons., New York, 1986) p. 145 (1986)
Oh SJ, Kwon SJ, Lee JY, Yoo JY, Choo WY, Corrosion, 58(6), 498 (2002)
Lee JY, Oh SJ, Sohn JG, Kwon SJ, Corr. Sci., Submitted for publication in (2002)

[1] Shastry CR, Friel JJ, Townsend HE, ASTM STP 965/ ASTM, pp.5, 1988 (1988)

[2] Shastry CR, Friel JJ,Townsend HE, ASTM STP 965 (Philadelphia, PA ASTM, 1988) 5 (1988)

[3] Townsend HE, Zoccola ZC, ASTM 767 (Philadelphia, PA ASTM, 1988) 45 (1988)

[4] Oh SJ, Ph.D Thesis, Old Dominion University, Department of Physics, 1997 (1997)

[5] Yun TS, J. Korean Institute of Metals and Materials, 15(2), 8 (1977)

[6] Dillon CP, Corrosion Control in the Chemical Process Industries (Materials Technology Institute of the Chemical Process Industries, Inc., 1994) (1994)

[7] Yamashita M, Miyuki H, Nagano H, Misawa T, Corro. Eng., 4, 43 (1994)

[8] Misawa T, Asami K, Hashimoto K, Shimodaira S, Corr. Sci., 14, 279 (1974)

[9] Suzuki I, Hisamatsu Y, J. Electrochem. Soc., 127(10), 2210 (1980)

[10] Stratmann M, Bohnenkamp K, Ramchandran T, Corr. Sci., 27(9), 905 (1987)

[11] Kihira H, Ito S, Murata T, Corr. Sci., 31, 383 (1990)

[12] Nishikayta A, Yamashita Y, Katayama H, Tsuru T, Usami A, Tanabe K, Mabuchi, Corr. Sci., 37, 2059 (1995)

[13] Yamashita M, Misawa T, Proc. 3rd NACE Am. Reging Corr. Cong. (1998)

[14] Miyuki H, Zairyo-to-Kankyo, 47, 186 (1998)

[15] Oh SJ, Kwon SJ, Cook DC, Townsend HE, Hyp. Int., C4, 37 (1999)

[16] Balasubramanian R, Cook DC, Perez T, Reyes J, Hyp. Int., C4, 37 (1999)

[17] Yamashita M, Nagano H, Misawa T, Townsend HE, ISIJ Int., 38, 285 (1998)

[18] Jackson E, Hydrometallurgical Extraction and Reclamation, (John Willey & Sons., New York, 1986) p. 145 (1986)

[19] Oh SJ, Kwon SJ, Lee JY, Yoo JY, Choo WY, Corrosion, 58(6), 498 (2002)

[20] Lee JY, Oh SJ, Sohn JG, Kwon SJ, Corr. Sci., Submitted for publication in (2002)