Preparation and characterization of imidazolium-PEO-based Ionene/PVDF(HFP)/LiTFSI as a novel Gel polymer electrolyte

Roshni Lilly Thankamony; Hodong Chu; Sanghyun Lim; Tae-Hyun Kim; Young-Jun Kim; Taeeun Yim

Macromolecular Research, Vol.23, No.1, 38-44, January, 2015

DOI10.1007/s13233-015-3001-9 Export Citation

Preparation and characterization of imidazolium-PEO-based Ionene/PVDF(HFP)/LiTFSI as a novel Gel polymer electrolyte

Roshni Lilly Thankamony, Hodong Chu, Sanghyun Lim, Tae-Hyun Kim^†, Young-Jun Kim¹, and Taeeun Yim¹

Organic Material Synthesis Laboratory, Department of Chemistry, Incheon National University, Incheon, 406-772, Korea
¹Advanced Batteries Research Center, Korea Electronics Technology Institute, Bundang-gu, Seongnam, Gyeonggi, 463-816, Korea

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The synthesis and properties of a solvent-free gel polymer electrolyte based on an imidazolium-poly(ethylene oxide) (PEO)-based ionene electrolyte, a poly(vinylidene fluoride-hexafluoropropylene) (PVDF(HFP)) support, and the lithium bis(trifluoromethane sulfonyl) imide (LiTFSI) salt are reported. A ternary gel polymer electrolyte film, produced from mixtures of the imidazolium-PEO-based ionene ([IPI][Br]), PVDF(HFP), and LiTFSI, displayed good thermal and mechanical stability. A very high room temperature conductivity of 2.6×10^(-3) S/cm and a broad electrochemical stability window were obtained, demonstrating the utility of the electrolyte for practical Li-ion battery applications.

Keywords:gel polymer electrolyte;imidazolium-PEO-based ionene;ionic conductivity;thermal stability;electrochemical stability

[References]

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Song MK, Cho JY, Cho BW, Rhee HW, J. Power Sources, 110(1), 209 (2002)
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Ohno H, Yoshizawa M, Ogihara W, Electrochim. Acta, 48(14-16), 2079 (2003)
Kim KS, Choi S, Demberelnyamba D, Lee H, Oh J, Lee BB, Mun SJ, Chem. Commun., 828 (2004)
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Appetecchi GB, Kim GT, Montanina M, Carewska M, Marcilla R, Mecerreyes D, De Meatza I, J. Power Sources, 195(11), 3668 (2010)
Erdmenger T, Perevyazko I, Vitz J, Pavlov G, Schubert US, J. Mater. Chem., 20, 3583 (2010)
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Abraham K, Alamgir M, J. Electrochem. Soc., 137, 1657 (1990)
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Croce F, Gerace F, Dautzemberg G, Passerini S, Appetecchi GB, Scrosati B, Electrochim. Acta, 39(14), 2187 (1994)
Capiglia C, Saito Y, Kataoka H, Kodama T, Quartarone E, Mustarelli P, Solid State Ion., 131(3-4), 291 (2000)
Li G, Li Z, Zhang P, Zhang H, Wu Y, Pure Appl. Chem., 80, 2553 (2008)
Yeon SH, Kim KS, Choi S, Cha JH, Lee H, J. Phys. Chem. B, 109(38), 17928 (2005)
Yu B, Zhou F, Wang C, Liu W, Eur. Polym. J., 43, 2699 (2007)
MacFarlane DR, Huang J, Forsyth M, Nature, 402, 792 (1999)
Munoz-Rojas D, Leriche JB, Delacourt C, Poizot P, Palacin MR, Tarascon JM, Electrochem. Commun., 9, 708 (2007)
Pandey GP, Hashmi SA, Agrawal RC, Solid State Ion., 179(15-16), 543 (2008)
Shin JH, Henderson WA, Appetecchi GB, Alessandrini E, Passerini S, Electrochim. Acta, 50(19), 3859 (2005)
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[Referenced By]

[1] Feuillade G, Perche P, J. Appl. Electrochem., 5, 63 (1975)

[2] Gray F, MacCallum J, Vincent C, Giles J, Macromolecules, 21, 392 (1988)

[3] Song JY, Wang YY, Wan CC, J. Power Sources, 77(2), 183 (1999)

[4] Dias FB, Plomp L, Veldhuis JBJ, J. Power Sources, 88(2), 169 (2000)

[5] Song MK, Cho JY, Cho BW, Rhee HW, J. Power Sources, 110(1), 209 (2002)

[6] Southall JP, Hubbard HV, Johnston SF, Rogers V, Davies GR, McIntyre JE, Ward IM, Solid State Ion., 85(1-4), 51 (1996)

[7] Ohno H, Yoshizawa M, Ogihara W, Electrochim. Acta, 48(14-16), 2079 (2003)

[8] Kim KS, Choi S, Demberelnyamba D, Lee H, Oh J, Lee BB, Mun SJ, Chem. Commun., 828 (2004)

[9] Wilkes JS, Zaworotko MJ, J. Chem. Soc. Chem. Commun., 965 (1992)

[10] Panozzo S, Armand M, Stephan O, Appl. Phys. Lett., 80, 679 (2002)

[11] Sakaebe H, Matsumoto H, Electrochem. Commun., 5, 594 (2003)

[12] Matsumi N, Sugai K, Miyake M, Ohno H, Macromolecules, 39(20), 6924 (2006)

[13] Pont AL, Marcilla R, De Meatza I, Grande H, Mecerreyes D, J. Power Sources, 188(2), 558 (2009)

[14] Yoshizawa M, Ogihara W, Ohno H, Polym. Adv. Technol., 13, 589 (2002)

[15] Ganapatibhotla LV, Zheng J, Roy D, Krishnan S, Chem. Mater., 22, 6347 (2010)

[16] Zhou Q, Boyle PD, Malpezzi L, Mele A, Shin JH, Passerini S, Henderson WA, Chem. Mater., 23, 4331 (2011)

[17] Washiro S, Yoshizawa M, Nakajima H, Ohno H, Polymer, 45(5), 1577 (2004)

[18] Dobbelin M, Azcune I, Bedu MI, Ruiz de Luzuriaga A, Genua A, Jovanovski V, Cabanero G, Odriozola I, Chem. Mater., 24, 1583 (2012)

[19] Appetecchi GB, Kim GT, Montanina M, Carewska M, Marcilla R, Mecerreyes D, De Meatza I, J. Power Sources, 195(11), 3668 (2010)

[20] Erdmenger T, Perevyazko I, Vitz J, Pavlov G, Schubert US, J. Mater. Chem., 20, 3583 (2010)

[21] Carlisle TK, Bara JE, Lafrate AL, Gin DL, Noble RD, J. Membr. Sci., 359(1-2), 37 (2010)

[22] Kelly I, Owen J, Steele B, J. Power Sources, 14, 13 (1985)

[23] Abraham K, Alamgir M, J. Electrochem. Soc., 137, 1657 (1990)

[24] Refaey SA, Elrehim SS, Electrochim. Acta, 42(4), 667 (1997)

[25] Croce F, Gerace F, Dautzemberg G, Passerini S, Appetecchi GB, Scrosati B, Electrochim. Acta, 39(14), 2187 (1994)

[26] Capiglia C, Saito Y, Kataoka H, Kodama T, Quartarone E, Mustarelli P, Solid State Ion., 131(3-4), 291 (2000)

[27] Li G, Li Z, Zhang P, Zhang H, Wu Y, Pure Appl. Chem., 80, 2553 (2008)

[28] Yeon SH, Kim KS, Choi S, Cha JH, Lee H, J. Phys. Chem. B, 109(38), 17928 (2005)

[29] Yu B, Zhou F, Wang C, Liu W, Eur. Polym. J., 43, 2699 (2007)

[30] MacFarlane DR, Huang J, Forsyth M, Nature, 402, 792 (1999)

[31] Munoz-Rojas D, Leriche JB, Delacourt C, Poizot P, Palacin MR, Tarascon JM, Electrochem. Commun., 9, 708 (2007)

[32] Pandey GP, Hashmi SA, Agrawal RC, Solid State Ion., 179(15-16), 543 (2008)

[33] Shin JH, Henderson WA, Appetecchi GB, Alessandrini E, Passerini S, Electrochim. Acta, 50(19), 3859 (2005)

[34] Kim GT, Appetecchi GB, Alessandrini F, Passerini S, J. Power Sources, 171(2), 861 (2007)

[35] Slane S, Salomon M, J. Power Sources, 55, 7 (1995)