Smart superabsorbent UV resistant etherified PVA gel: Synthesis and characterization

Ayan Dey; Rabin Bera; Sabbir Ahmed; Debabrata Chakrabarty

Journal of Industrial and Engineering Chemistry, Vol.21, 1219-1230, January, 2015

DOI10.1016/j.jiec.2014.05.038 Export Citation

Smart superabsorbent UV resistant etherified PVA gel: Synthesis and characterization

Ayan Dey, Rabin Bera, Sabbir Ahmed, and Debabrata Chakrabarty^†

Department of Polymer Science and Technology, University of Calcutta, 92, A.P.C. Road, Kolkata 700009, India

E-mail:

Polyvinyl alcohol (PVA) is etherified with ethane-1,2-diol to obtain smart etherified polyvinyl alcohol (EPVA) having improved mechanical and gelling characteristics. Linear EPVA is deficient in swelling compared to PVA and follows first order swelling kinetics. EPVA when converted to gel with 5% crosslinker (EPVA5) shows maximum swelling and mechanicals. Sustained solvent releasing ability of the EPVA gel is evident from the deswelling study. EPVA gels demonstrate an increase in storage modulus with increase in crosslinker dose. Ultraviolet resistance ability of the EPVA gel is maximum in the UV range of 280-320 nm. EPVA5 exhibits cells of nanometric dimensions.

Keywords:Hydrogel;Thermoresponsive;Raman spectroscopy;Rheology;UV resistance;Electron microscopy

[References]

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[Referenced By]

[1] Zhang JT, Huang SW, Xue YN, Zhuo RX, Macromol. Rapid Commun., 26(16), 1346 (2005)

[2] Luo YL, Yu W, Xu F, Zhang LL, J. Polym. Sci. A: Polym. Chem., 50(10), 2053 (2012)

[3] Gumusderelioglu M, Topal IU, Radiat. Phys. Chem., 73, 272 (2005)

[4] Wang Y, Mingyuan X, Wei J, Li C, Zhang R, Cao H, Yang J, Tan T, RSC Adv., 2, 11592 (2012)

[5] Miyata T, Asami N, Uragami T, Nature, 399(6738), 766 (1999)

[6] Amidon GL, Mol. Pharm., 1, 85 (2004)

[7] Pakulska MM, Ballios BG, Shoichet MS, Biomed. Mater., 7, 1 (2012)

[8] Smith LE, Rimmer S, MacNeil S, Biomaterials, 27, 2806 (2006)

[9] Satarkar NS, Hilt JZ, Acta Biomater., 4, 11 (2008)

[10] Huang X, Lowe TL, Biomacromolecules, 6(4), 2131 (2005)

[11] Jang JH, Jhaveri SJ, Rasin B, Koh C, Ober CK, Thomas EL, Nano Lett., 8, 1456 (2008)

[12] Prabaharan M, Mano JF, Macromol. Biosci., 6, 991 (2006)

[13] Qiu Y, Park K, Adv. Drug Deliv. Rev., 53, 321 (2001)

[14] Sangeetha NM, Maitra U, Chem. Soc. Rev., 34, 821 (2005)

[15] Ahn SK, Kasi RM, Kim SC, Sharmaa N, Zhou YX, Soft Matter, 4, 1151 (2008)

[16] Yano S, Kurita K, Iwata K, Furukawa T, Kodomari M, Polymer, 44(12), 3515 (2003)

[17] Mansur HS, Vasconcelos WL, Orefice RL, J. Non-Cryst. Solids, 273(1-3), 109 (2000)

[18] Mansur HS, Lobato ZP, Orefice RL, Vasconcelos WL, Oliveira C, Machado LJ, Biomacromolecules, 1(4), 789 (2000)

[19] Mansur HS, Mansur AAP, Mater. Res. Soc. Symp. Proc., 20, 873E (2005)

[20] Hosseinzadeh H, Curr. Chem. Lett., 2, 153 (2013)

[21] Yun J, Im JS, Lee YS, Yoo SJ, Kim HI, J. Appl. Polym. Sci., 120(2), 1050 (2011)

[22] Zhang JT, Bhat R, Jandt KD, Acta Biomater, 5(1), 488 (2009)

[23] Tang YF, Du YM, Hu XW, Shi XW, Kennedy JF, Carbohydr. Polym., 67(4), 491 (2007)

[24] Gupta A, Upadhyay NK, Parthasarathy S, Rajagopal C, Roy PK, J. Appl. Polym. Sci., 128(6), 4031 (2013)

[25] Wenceslau AC, Santos FGD, Ramos ERF, Nakamura CV, Rubira AF, Muniz EC, Mater. Sci. Eng. B-Solid State Mater. Adv. Technol., 1259 (2012)

[26] Sakai S, Tsumura M, Inoue M, Koga Y, Fukano K, Taya M, J. Mater. Chem., http://dx.doi.org/10.1039/C3TB20780C., B20780 (2013)

[27] Arndt K, Schmidt T, Menge H, Macromol. Symp., 164(1), 313 (2001)

[28] Klug HP, Alexander LE, X-Ray Diffraction Procedures, 2nd edn., John Wiley & Sons, New York, 1974, pp. 687-703.

[29] Moran JI, Alvarez VA, Cyras VP, Vazquez A, Cellulose, 15, 149 (2008)

[30] El-Hamshary H, Eur. Polym. J., 43, 4830 (2007)

[31] Ruiz J, Mantecon A, Cadiz V, Polymer, 42(15), 6347 (2001)

[32] Berger J, Reist M, Mayer JM, Felt O, Peppas NA, Gurny R, Eur. J. Pharm. Biopharm., 57, 19 (2004)

[33] White EM, Yatvin J, Grubbs JB, Bilbrey JA, Locklin J, J. Polym. Sci. B: Polym. Phys., 51(14), 1084 (2013)

[34] Stefanescu M, Stoia M, Stefanescu O, Davidescu C, Vlaseb G, Sfırloagac P, RevueRoum. Chim., 55(1), 17 (2010)

[35] Singh R, Kulkarni SG, Channe SS, Polym. Bull., 70(4), 1251 (2013)

[36] Stuart BH, Vib. Spectrosc., 10, 79 (1996)

[37] Carey FA, Organic Chemistry, 4th edn, McGraw-Hill Higher Education, USA, 2000, pp. 668-672.

[38] Hema M, Selvasekarapandian S, Hirankumar G, Sakunthala A, Arunkumara D, Nithya H, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 75, 474 (2010)

[39] Ricciardi R, Auriemma F, De Rosa C, Laupretre F, Macromolecules, 37(5), 1921 (2004)

[40] Liu XW, Zhu S, Wu SR, Wang P, Han GZ, Colloids Surf. A: Physicochem. Eng. Asp., 417, 140 (2013)

[41] Masuda Y, Tanaka T, Nakanishi T, Colloid Polym. Sci., 279(12), 1241 (2001)

[42] Porter TL, Stewart R, Reed J, Morton K, Sensors, 7, 1980 (2007)

[43] Annabi N, Nichol JW, Zhong X, Ji C, Koshy S, Khademhosseini A, Dehghani F, Tissue Eng. Part B, 16(4), 371 (2010)

[44] Courtois J, Bystrom E, Irgum K, Polymer, 47(8), 2603 (2006)

[45] Zhang Q, Jiang Y, Zhang Y, Ye Z, Tan W, Lang M, Polym. Degrad. Stabil., 98, 209 (2013)

[46] Schmaljohann D, Adv. Drug Deliv. Rev., 58, 1655 (2006)

[47] Schulza J, Hohenberg H, Pflucker F, Gartner E, Will T, Pfeiffer S, Wep R, Wendel V, Gers-Barlag H, Wittern KP, Adv. Drug Deliv. Rev., 54, S157 (2002)

[48] Serpone N, Dondi D, Albini A, Inorg. Chim. Acta., 360, 794 (2007)