Solvent-free aerobic oxidation of ethylbenzene over Mn-containing silylated MgAl layered double hydroxides

Lei Yang; Binbin Fan; Xingyu Cui; Xiufeng Shi; Ruifeng Li

Journal of Industrial and Engineering Chemistry, Vol.21, 689-695, January, 2015

DOI10.1016/j.jiec.2014.03.038 Export Citation

Solvent-free aerobic oxidation of ethylbenzene over Mn-containing silylated MgAl layered double hydroxides

Lei Yang, Binbin Fan^†, Xingyu Cui, Xiufeng Shi, and Ruifeng Li^{1, †}

Institute of Special Chemicals, Taiyuan University of Technology, Taiyuan 030024, PR China
¹Key Laboratory of Coal Science and Technology MOE, Taiyuan University of Technology, Taiyuan 030024, PR China

E-mail:,

A novel method for the preparation of Mn-containing silylated layered double hydroxides (LDHs) is presented. The method involves functionalizing the calcined MgAl LDH (LDO) with dimethoxydiphenylsilane (DDS), and then treating it in the aqueous solution of KMnO4 under Ar. The prepared Mncontaining silylated MgAl LDH catalysts have higher Mn amount and more accessible Mn sites than the corresponding Mn-containing MgAl LDH catalysts, and exhibited much higher catalytic activity in the oxidation of ethylbenzene with O2 in the absence of organic solvents than the latter. In addition, the prepared Mn-containing silylated MgAl LDH catalyst was highly stable and reusable.

Keywords:LDHs;Silylated LDHs;Ethylbenzene oxidation;O2

[References]

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[2] Corma A, Garcia H, Chem. Rev., 102(10), 3837 (2002)

[3] Jana SK, Wu P, Tatsumi T, J. Catal., 240(2), 268 (2006)

[4] Matsushita T, Ebitani K, Kaneda K, Chem. Commun., 3, 265 (1999)

[5] Kamata K, Kasai J, Yamaguchi K, Mizuno N, Org. Lett., 6, 3577 (2004)

[6] Barbiero G, Kim WG, Hay AS, Tetrahedron Lett., 35, 5833 (1994)

[7] Smith JRL, Iamamoto Y, Vinhado FS, J. Mol. Catal. A-Chem., 252(1-2), 23 (2006)

[8] Ghiaci M, Molaie F, Sedaghat ME, Dorostkar N, Catal. Commun., 11, 694 (2010)

[9] Qi J, Ma H, Li X, Zhou Z, Choi MC, Chan A, Yang Q, Chem. Commun., 11, 1294 (2003)

[10] Yamaguchi K, Mizuno N, New J. Chem., 26, 972 (2002)

[11] Tusar NN, Laha SC, Cecowski S, Arcon I, Kaucic V, Glaser R, Microporous Mesoporous Mater., 146, 166 (2011)

[12] Velu S, Shah N, Jyothi TM, Sivasanker S, Microporous Mesoporous Mater., 33, 61 (1999)

[13] Jana SK, Kubota Y, Tatsumi T, J. Catal., 247(2), 214 (2007)

[14] Dimotakis ED, Pinnavaia TJ, Inorg. Chem., 29, 2393 (1990)

[15] Hutson ND, Speakman SA, Payzant EA, Chem. Mater., 16, 4135 (2004)

[16] You YW, Zhao HT, Vance GF, J. Mater. Chem., 12, 907 (2002)

[17] Domingo C, Loste E, Fraile J, J. Supercrit. Fluids, 37(1), 72 (2006)

[18] Rives V, Ulibarri MA, Coord. Chem. Rev., 181, 61 (1999)

[19] Li F, Duan X, Struct. Bond., 119, 193 (2006)

[20] Vaccari A, Appl. Clay Sci., 14, 161 (1999)

[21] Perez-Ramırez J, Abello S, van der Pers NM, Chem. Eur. J., 13, 870 (2007)

[22] Tao Q, He HP, Frost RL, Yuan P, Zhu JX, Appl. Surf. Sci., 255(7), 4334 (2009)

[23] Chimentao RJ, Abello S, Medina F, Llorca J, Sueiras JE, Cesteros Y, Salagre P, J. Catal., 252(2), 249 (2007)

[24] Winter F, van Dillen AJ, de Jong KP, Chem. Commun., 31, 3977 (2005)

[25] Abello S, Medina F, Tichit D, Perez-Ramirez J, Cesteros Y, Salagre P, Sueiras JE, Chem. Commun., 11, 1453 (2005)

[26] Choudhary VR, Indurkar JR, Narkhede VS, Jha R, J. Catal., 227(1), 257 (2004)

[27] Zhu JX, Yuan P, He HP, Frost R, Tao Q, Shen W, Bostrom T, J. Colloid Interface Sci., 319(2), 498 (2008)

[28] Gardella JA, Ferguson SA, Chin RL, Appl. Spectrosc., 40, 224 (1986)

[29] Umezawa Y, Reilley CN, Anal. Chem., 50, 1290 (1978)

[30] Stanimirova TS, Kirov G, Dinolova E, J. Mater. Sci., 20, 453 (2001)

[31] Cardoso LP, Valim JB, J. Phys. Chem. Solids, 65, 481 (2004)

[32] Hibino T, Tsunashima A, Chem. Mater., 10, 4055 (1998)

[33] Ulibarri MA, Pavlovic I, Hermosin MC, Cornejo J, Appl. Clay Sci., 10, 131 (1995)

[34] Adachi-Pagano M, Forano C, Besse JP, J. Mater. Chem., 13, 1988 (2003)

[35] Chen JD, Sheldon RA, J. Catal., 153(1), 1 (1995)

[36] Bernal HG, Caero LC, Finocchio E, Busca G, Appl. Catal. A: Gen., 369(1-2), 27 (2009)

[37] Paul H, Small RD, Scaiano JC, J. Am. Chem. Soc., 100, 4520 (1978)

[38] Toribio PP, Campos-Martin JM, Fierro JLG, J. Mol. Catal. A-Chem., 227(1-2), 101 (2005)

[39] Vadakkekara R, Chakraborty M, Parikh PA, Ind. Eng. Chem. Res., 51(16), 5691 (2012)

[40] Arshadi M, Ghiaci M, Appl. Catal. A: Gen., 399(1-2), 75 (2011)

[41] Fukuda O, Sakaguchi S, Ishii Y, Adv. Synth. Catal., 343, 809 (2001)

[42] Arshadi M, Ghiaci M, Rahmanian A, Ghaziaskar H, Gil A, Appl. Catal. B: Environ., 119, 81 (2012)

[43] Guo CC, Peng QJ, Liu Q, Jiang GF, J. Mol. Catal. A-Chem., 192(1-2), 295 (2003)

[44] Kirm I, Medina F, Rodriguez X, Cesteros Y, Salagre P, Sueiras J, Appl. Catal. A: Gen., 272(1-2), 175 (2004)