Highly selective micro-porous ZIF-8 membranes prepared by rapid electrospray deposition

Vıctor Manuel Aceituno Melgar; Howon Ahn; Jinsoo Kim; Mohd Roslee Othman

Journal of Industrial and Engineering Chemistry, Vol.21, 575-579, January, 2015

DOI10.1016/j.jiec.2014.03.021 Export Citation

Highly selective micro-porous ZIF-8 membranes prepared by rapid electrospray deposition

Vıctor Manuel Aceituno Melgar¹, Howon Ahn¹, Jinsoo Kim^{1, †}, and Mohd Roslee Othman^{1, 2, †}

¹Department of Chemical Engineering, Kyung Hee University, 1732 Deogyeong-daero, Giheung-gu, Yongin-si, Gyeonggi-do 446-701, Republic of Korea
²School of Chemical Engineering, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang, Malaysia

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Highly selective ZIF-8 membranes were successfully prepared by electrospray deposition for H2/CO2 separation. This novel method produced ZIF-8membranes in a facile and time-efficientmanner using an electrostatic force-assisted coating approach. In addition, the membrane thickness could be controlled easily by simply varying the deposition time. Results from the experiment indicate that the membrane performed preeminently in comparison with previously reported glassy and polymeric membranes for H2/CO2 separation. The H2 permeance of the ZIF-8 membrane prepared at 70 ℃ for 55.71 min was 4.23 × 10-7 mol m-2 s-1 Pa-1 with H2/CO2 selectivity of 20.3.

Keywords:ZIF-8 membranes;Electrospray deposition;Gas separation;Hydrogen;Carbon dioxide

[References]

Wender I, Fuel Process. Technol., 48(3), 189 (1996)
Helwani Z, Wiheeb AD, Kim J, Othman MR, Energy Sources Part A-Recovery Util. Environ. Eff., http://dx.doi.org/10.1080/15567036.2013.813991 (in press) (2014)
Lee JS, Jhung SH, Yoon JW, Hwang YK, Chang JS, J. Ind. Eng. Chem., 15(5), 674 (2009)
Othman MR, Fernando WJN, Kim J, Adsorpt. Sci. Technol., 28, 179 (2010)
Wiheeb AD, Ahmad MA, Murat MN, Kim J, Othman MR, J. Porous Media, 17, 159 (2014)
Ahn H, Kim D, Melgar VMA, Kim J, Othman MR, Nguyen HVP, Han J, Yoon SP, J. Ind. Eng. Chem., http://dx.doi.org/10.1016/j.jiec.2013.12.069 (2014)
Arjmandi M, Pakizeh M, J. Ind. Eng. Chem., http://dx.doi.org/10.1016/j.jiec.2013.12.091 (2014)
Rajabi Z, Moghadassi AR, Hosseini SM, Mohammadi M, J. Ind. Eng. Chem., 19(1), 347 (2013)
Shah M, McCarthy MC, Sachdeva S, Lee AK, Jeong HK, Ind. Eng. Chem. Res., 51(5), 2179 (2012)
Xu GS, Yao JF, Wang K, He L, Webley PA, Chen CS, Wang HT, J. Membr. Sci., 385(1-2), 187 (2011)
Phan A, Doonan CJ, Uribe-Romo FJ, Knobler CB, O’keeffe M, Yaghi OM, Acc. Chem. Res., 43, 58 (2010)
Hara N, Yoshimune M, Negishi H, Haraya K, Hara S, Yamaguchi T, J. Membr. Sci., 450, 215 (2014)
Gascon J, Kapteijn F, Zornoza B, Sebastian V, Casado C, Coronas J, Chem. Mater., 24, 2829 (2012)
Pan YC, Li T, Lestari G, Lai ZP, J. Membr. Sci., 390, 93 (2012)
Tao K, Kong CL, Chen L, Chem. Eng. J., 220, 1 (2013)
Xie Z, Yang J, Wang J, Bai J, Yin H, Yuan B, Lu J, Zhang Y, Zhou L, Duan C, Chem. Commun., 48, 5977 (2012)
Hogan CJ, Biswas P, Aerosol Sci. Technol., 42, 75 (2008)
Balachandran W, Miao P, Xiao P, J. Electrostat., 50, 249 (2001)
Lintanf A, Neagu R, Djurado E, Solid State Ion., 177(39-40), 3491 (2007)
Kwon HT, Kim J, Park JH, J. Korean Phys. Soc., 54, 1223 (2009)
Pan Y, Wang B, Lai Z, J. Membr. Sci. (2012)
Bux H, Liang FY, Li YS, Cravillon J, Wiebcke M, Caro J, J. Am. Chem. Soc., 131(44), 16000 (2009)
Fan L, Xue M, Kang Z, Li H, Qiu S, J. Mater. Chem., 22, 25272 (2012)
Robeson LM, J. Membr. Sci., 320(1-2), 390 (2008)

[Referenced By]

[Related Articles]

[1] Wender I, Fuel Process. Technol., 48(3), 189 (1996)

[2] Helwani Z, Wiheeb AD, Kim J, Othman MR, Energy Sources Part A-Recovery Util. Environ. Eff., http://dx.doi.org/10.1080/15567036.2013.813991 (in press) (2014)

[3] Lee JS, Jhung SH, Yoon JW, Hwang YK, Chang JS, J. Ind. Eng. Chem., 15(5), 674 (2009)

[4] Othman MR, Fernando WJN, Kim J, Adsorpt. Sci. Technol., 28, 179 (2010)

[5] Wiheeb AD, Ahmad MA, Murat MN, Kim J, Othman MR, J. Porous Media, 17, 159 (2014)

[6] Ahn H, Kim D, Melgar VMA, Kim J, Othman MR, Nguyen HVP, Han J, Yoon SP, J. Ind. Eng. Chem., http://dx.doi.org/10.1016/j.jiec.2013.12.069 (2014)

[7] Arjmandi M, Pakizeh M, J. Ind. Eng. Chem., http://dx.doi.org/10.1016/j.jiec.2013.12.091 (2014)

[8] Rajabi Z, Moghadassi AR, Hosseini SM, Mohammadi M, J. Ind. Eng. Chem., 19(1), 347 (2013)

[9] Shah M, McCarthy MC, Sachdeva S, Lee AK, Jeong HK, Ind. Eng. Chem. Res., 51(5), 2179 (2012)

[10] Xu GS, Yao JF, Wang K, He L, Webley PA, Chen CS, Wang HT, J. Membr. Sci., 385(1-2), 187 (2011)

[11] Phan A, Doonan CJ, Uribe-Romo FJ, Knobler CB, O’keeffe M, Yaghi OM, Acc. Chem. Res., 43, 58 (2010)

[12] Hara N, Yoshimune M, Negishi H, Haraya K, Hara S, Yamaguchi T, J. Membr. Sci., 450, 215 (2014)

[13] Gascon J, Kapteijn F, Zornoza B, Sebastian V, Casado C, Coronas J, Chem. Mater., 24, 2829 (2012)

[14] Pan YC, Li T, Lestari G, Lai ZP, J. Membr. Sci., 390, 93 (2012)

[15] Tao K, Kong CL, Chen L, Chem. Eng. J., 220, 1 (2013)

[16] Xie Z, Yang J, Wang J, Bai J, Yin H, Yuan B, Lu J, Zhang Y, Zhou L, Duan C, Chem. Commun., 48, 5977 (2012)

[17] Hogan CJ, Biswas P, Aerosol Sci. Technol., 42, 75 (2008)

[18] Balachandran W, Miao P, Xiao P, J. Electrostat., 50, 249 (2001)

[19] Lintanf A, Neagu R, Djurado E, Solid State Ion., 177(39-40), 3491 (2007)

[20] Kwon HT, Kim J, Park JH, J. Korean Phys. Soc., 54, 1223 (2009)

[21] Pan Y, Wang B, Lai Z, J. Membr. Sci. (2012)

[22] Bux H, Liang FY, Li YS, Cravillon J, Wiebcke M, Caro J, J. Am. Chem. Soc., 131(44), 16000 (2009)

[23] Fan L, Xue M, Kang Z, Li H, Qiu S, J. Mater. Chem., 22, 25272 (2012)

[24] Robeson LM, J. Membr. Sci., 320(1-2), 390 (2008)