화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.21, 356-362, January, 2015
Industrial application of photocatalysts prepared by hydrothermal and sol-gel methods
E-mail:
TiO2-containing almond shell activated carbons (TiO2/ASAC) with high photocatalytic activity were prepared using hydrothermal and sol-gel methods. The prepared photocatalysts were characterized by different techniques. XRD study confirmed that TiO2 existed in a mixture of anatase and rutile phase. Nano-TiO2 particles were dispersed on the ASAC with the size of 18-24 nm. The specific surface area of the samples decreased from 1398 m2/g to 661 m2/g indicating that the pores of activated carbon are blocked by TiO2. The photocatalyst obtained from the hydrothermal process is better than the other samples one in a comparison of the anatase content, and was also confirmed by the photocatalytic degradation of Total Organic Carbon (TOC) from industrial phosphoric acid solution under UV irradiation.
  1. Huang Q, Hong CS, Chemosphere, 41, 871 (2000)
  2. Ai ZH, Yang P, Lu XH, J. Hazard. Mater., 124(1-3), 147 (2005)
  3. Zhu XL, Yuan CW, Bao YC, Yang JH, Wu YZ, J. Mol. Catal. A-Chem., 229(1-2), 95 (2005)
  4. Nguyen-Phan TD, Shin EW, J. Ind. Eng. Chem., 17(3), 397 (2011)
  5. Panniello A, Curri ML, Diso D, Licciulli A, Locaputo V, Agostiano A, Comparelli R, Mascolo G, Appl. Catal. B: Environ., 122, 190 (2012)
  6. Sopyan I, Watanabe M, Murasawa S, Hashimoto K, Fujishima A, J. Photochem. Photobiol. A-Chem., 98, 79 (1996)
  7. Peill NJ, Hoffmann MR, Environ. Sci. Technol., 30, 2806 (1996)
  8. Fernandez A, Lassaletta G, Jimenez VM, Justo A, Gonzalezelipe AR, Herrmann JM, Tahiri H, Aitichou Y, Appl. Catal. B: Environ., 7(1-2), 49 (1995)
  9. Grieken R, Aguado J, Lopez-Munoz MJ, Marugan J, J. Photochem. Photobiol. A-Chem., 148, 315 (2002)
  10. Sayılkan F, Asilturk M, Sener S, Erdemoglu S, Erdemoglu M, Sayılkan H, Turk. J. Chem., 31, 211 (2007)
  11. Hosseini SN, Borghei SM, Vossoughi M, Taghavinia N, Appl. Catal. B: Environ., 74(1-2), 53 (2007)
  12. Mogyorosi K, Dekany I, Fendler JH, Langmuir, 19(7), 2938 (2003)
  13. Awate SV, Suzuki K, Adsorption, 7, 319 (2001)
  14. Shankar MV, Anandan S, Venkatachalam N, Arabindoo B, Murugesan V, Chemosphere, 63, 1014 (2006)
  15. Le HA, Linh LT, Chin S, Jurng J, Powder Technol., 225, 167 (2012)
  16. Baek MH, Jung WC, Yoon JW, Hong JS, Lee YS, Suh JK, J. Ind. Eng. Chem., 19(2), 469 (2013)
  17. Baek MH, Yoon JW, Hong JS, Suh JK, Appl. Catal. A: Gen., 450, 222 (2013)
  18. Zhu B, Zou L, J. Environ. Manage., 90, 3217 (2009)
  19. Omri A, Benzina M, Trabelsi W, Ammar N, Desalin. Water Treat., 10.1080/19443994.2013.800003, 1 (2013)
  20. Omri A, Wali A, Benzina M, Arab. J. Chem., 10.1016/j.arabjc.2012.04.047 (2012)
  21. Omri A, Benzina M, Alexandria Eng. J., 51, 343 (2012)
  22. Omri A, Benzina M, J. Soc. Chim. Tunisie, 14, 175 (2012)
  23. Le Leuch LM, Bandosz TJ, Carbon, 45, 568 (2007)
  24. Yoneyama H, Torimoto T, Catal. Today, 58(2-3), 133 (2000)
  25. Torimoto T, Kuwabata ISS, Yoneyama H, Environ. Sci. Technol., 30, 1275 (1996)
  26. Li Y, Li X, Li J, Yin J, Water Res., 40(6), 1119 (2006)
  27. Liu SX, Chen XY, Chen X, J. Hazard. Mater., 143(1-2), 257 (2007)
  28. Lu MC, Chen JN, Chang KT, Chemosphere, 38, 617 (2004)
  29. Jeong J, Sekiguchi K, Sakamoto K, Chemosphere, 57, 663 (2004)
  30. El-Sheikh AH, Sweileh JA, Talanta, 71, 1867 (2007)
  31. Aruldoss U, Kennedy LJ, Vijaya JJ, Sekaran G, J. Colloid Interface Sci., 355(1), 204 (2011)
  32. Becker P, Phosphates and Phosphoric Acid, Raw Materials, in: Technology and Economics of the Wet Process, 2nd ed., Marcel Dekker, Inc, New York, 1989.
  33. Mellah A, Benachour D, Ann. Chim. Sci. Mater., 32, 488 (2007)
  34. Nasr B, Hedi B, Abdellatif G, Rodrigo MA, Chem. Eng. Technol., 28(2), 193 (2005)
  35. Silem A, Boualia A, Mellah A, Kada R, Can. J. Appl. Spectrosc., 36, 94 (1991)
  36. Omri A, Benzina M, Ammar N, J. Ind. Eng. Chem., 19(6), 2092 (2013)
  37. Bergeret G, Gallezot P, in: Ertl G, Knozinger H, Weitkamp J (Eds.), Handbook of Heterogeneous Catalysis, Wiley-VCH, Weinheim, 1997, p. 439.
  38. Stoeckli F, Characterization of microporous carbons by adsorption and immersion techniques, in: J. Patrick (Ed.), Porosity in Carbons-Characterization and Applications, Arnold, London, 1995, p. 67.
  39. Wang ZH, Chen Y, Zhou C, Whiddon R, Zhang YW, Zhou JH, Cen KF, Int. J. Hydrog. Energy, 36(1), 216 (2011)
  40. Yu JG, Yu JC, Ho WK, Leung MKP, Cheng B, Zhang GK, Zhao XJ, Appl. Catal. A: Gen., 255(2), 309 (2003)
  41. Braconnier B, Paez CA, Lambert S, Alie C, Henrist C, Poelman D, Pirard JP, Cloots R, Heinrichs B, Microporous Mesoporous Mater., 122, 247 (2009)
  42. Spurr RA, Myers H, Anal. Chem., 29, 760 (1957)
  43. Nolan N, Pillai S, Seery M, J. Phys. Chem. C, 113, 16151 (2009)
  44. Yu JG, Zhou MH, Cheng B, Zhao XJ, J. Mol. Catal. A-Chem., 246(1-2), 176 (2006)
  45. Kim S, Ehrman SH, J. Colloid Interface Sci., 338(1), 304 (2009)
  46. Ambrus Z, Mogyorosi K, Szalai A, Alapi T, Demeter K, Dombi A, Sipos P, Appl. Catal. A: Gen., 340(2), 153 (2008)
  47. Li YJ, Li LY, Li CW, Chen W, Zeng MX, Appl. Catal. A: Gen., 427, 1 (2012)
  48. Chen YF, Lee CY, Yeng MY, Chiu HT, J. Cryst. Growth, 247(3-4), 363 (2003)
  49. Kishimoto T, Kozuka H, J. Mater. Res., 18, 466 (2003)
  50. Wang XJ, Hu ZH, Chen YJ, Zhao GH, Liu YF, Wen ZB, Appl. Surf. Sci., 255(7), 3953 (2009)
  51. Helali S, Puzenat E, Perol N, Safi MJ, Guillard C, Appl. Catal. A: Gen., 402(1-2), 201 (2011)
  52. Ahmed S, Rasul MG, Brown R, Hashib MA, J. Environ. Manage., 92, 311 (2011)
  53. Baek MH, Yoon JW, Hong JS, Suh JK, Appl. Catal. A: Gen., 450, 222 (2013)
  54. Xue G, Liu HH, Chen QY, Hills C, Tyrer M, Innocent F, J. Hazard. Mater., 186(1), 765 (2011)
  55. Tsai WT, Lee MK, Su TY, Chang YM, J. Hazard. Mater., 168(1), 269 (2009)
  56. Najar S, Fraj AB, Zammouri A, Ouederni A, Ratel A, J. Mater. Sci. Technol., 10, 73 (2002)
  57. Hamza W, Chtara C, Benzina M, J. Chem., http://www.hindawi.com/journals/jchem/aip/218786/ (2014)
  58. Belfadhel H, RATEL A, Ouederni A, Besr S, MORA JC, Ozone Sci. Eng., 17, 637 (1995)