Journal of Industrial and Engineering Chemistry, Vol.21, 350-355, January, 2015
Partial least squares modeling and analysis of furfural production from biomass-derived xylose over solid acid catalysts
E-mail:
Solid acid catalysts based on silica.alumina (SiO2-Al2O3) were used for promoting furfural production from D-xylose, and the partial least squares model was applied to develop an empirical kinetic model. Considering the experimental error and measurement noise, ~85% of variances for the output block comprising the D-xylose conversion and selectivities were used by employing three latent variables, and the comparison between experimental and simulation results demonstrated the effectiveness of the model. The effects of the operating conditions, including xylose concentration, temperature, and space velocity were evaluated using the developed model, and optimal conditions for the maximum furfural productivity were determined.
Keywords:D-xylose dehydration;Furfural;Solid acid catalyst;Kinetic model;Partial least square;Optimization
- Lange JP, van der Heide E, van Buijtenen J, Price R, Chem. Sus. Chem., 5, 150 (2012)
- Antal MJ, Leesomboon T, Mok WS, Richards GN, Carbohydr. Res., 217, 71 (1991)
- Antunes MM, Lima S, Fernandes A, Pillinger M, Ribeiro MF, Valente AA, Appl. Catal. A: Gen., 417-418, 243 (2012)
- Lamminpaa K, Ahola J, Tanskanen J, Ind. Eng. Chem. Res., 51(18), 6297 (2012)
- Marcotullio G, Jong WD, Green Chem., 12, 1739 (2010)
- Weingarten R, Cho J, Conner JWC, Huber GW, Green Chem., 12, 1423 (2010)
- Yang W, Li P, Bo D, Chang H, Carbohydr. Res., 357, 53 (2012)
- Zhang JH, Lin L, Liu SJ, Energy Fuels, 26(7), 4560 (2012)
- Martin C, Jonsson LJ, Enzyme Microb. Technol., 32(3-4), 386 (2003)
- Zeitsch KJ, The Chemistry and Technology of Furfural and its Many By-Products, Elsevier Science, Amsterdam, 2000.
- Aida TM, Shiraishi N, Kubo M, Watanabe M, Smith RL, J. Supercrit. Fluids, 55(1), 208 (2010)
- Jing Q, Lu XY, Chin. J. Chem. Eng., 15(5), 666 (2007)
- Kim S, Lee M, Park E, Lee S, Lee H, Park K, Park MJ, React. Kinet. Catal. Lett., 103, 267 (2011)
- Garcia-Sancho C, Sadaba I, Moreno-Tost R, Merida-Robles J, Santamaria-Gonzalez J, Lopez-Granados M, Maireles-Torres P, ChemSusChem, 6, 635 (2013)
- Kim SB, You SJ, Kim YT, Lee SM, Lee H, Park K, Park ED, Korean J. Chem. Eng., 28(3), 710 (2011)
- Lima S, Antunes MM, Fernandes A, Pillinger M, Ribeiro MF, Valente AA, Appl. Catal. A: Gen., 388(1-2), 141 (2010)
- Lima S, Fernandes A, Antunes MM, Pillinger M, Ribeiro F, Valente AA, Catal. Lett., 135(1-2), 41 (2010)
- Moreau C, Durand R, Peyron D, Duhamet J, Rivalier P, Ind. Crop. Prod., 7, 95 (1998)
- Agirrezabal-Telleria I, Requies J, Guemez MB, Arias PL, Appl. Catal. B: Environ., 145, 34 (2014)
- Crisci AJ, Tucker MH, Lee MY, Jang SG, Dumesic JA, Scott SL, ACS Catal., 1, 719 (2011)
- Dias AS, Pillinger M, Valente AA, J. Catal., 229(2), 414 (2005)
- Shi X, Wu Y, Li P, Yi H, Yang M, Wang G, Carbohydr. Res., 346, 480 (2011)
- Agirrezabal-Telleria I, Larreategui A, Requies J, Guemez MB, Arias PL, Bioresour. Technol., 102(16), 7478 (2011)
- Dias AS, Lima S, Pillinger M, Valente AA, Carbohydr. Res., 341, 2946 (2006)
- Dias AS, Pillinger M, Valente AA, Appl. Catal. A: Gen., 285(1-2), 126 (2005)
- Dias AS, Lima S, Carriazo D, Rives V, Pillinger M, Valente AA, J. Catal., 244(2), 230 (2006)
- Agirrezabal-Telleria I, Hemmann F, Jager C, Arias PL, Kemnitz E, J. Catal., 305, 81 (2013)
- Antunes MM, Lima S, Fernandes A, Candeias J, Pillinger M, Rocha SM, Ribeiro MF, Valente AA, Catal. Today, 195(1), 127 (2012)
- Chareonlimkun A, Champreda V, Shotipruk A, Laosiripojana N, Fuel, 89(10), 2873 (2010)
- Sadaba I, Lima S, Valente AA, Granados ML, Carbohydr. Res., 346, 2785 (2011)
- Suzuki T, Yokoi T, Otomo R, Kondo JN, Tatsumi T, Appl. Catal. A: Gen., 408(1-2), 117 (2011)
- Tanabe K, Holderich WF, Appl. Catal. A: Gen., 181(2), 399 (1999)
- You SJ, Kim YT, Park ED, React. Kinet. Catal. Lett., 10.1007/s11144-013-0655-1 (2013)
- Geladi P, Kowalski BR, Anal. Chim. Acta, 185, 1 (1986)
- Sharaf MA, Illman DL, Kowalski BR, Chemometrics, John Wiley & Sons, New York, 1986.
- Baffi G, Martin EB, Morris AJ, Comput. Chem. Eng., 23(3), 395 (1999)
- Park MJ, Dokucu MT, Doyle FJ, Ind. Eng. Chem. Res., 43(23), 7227 (2004)
- Lee MR, Park MJ, Jeon W, Choi JW, Suh YW, Suh DJ, Korean J. Chem. Eng., 28(11), 2142 (2011)
- Mosier N, Wyman C, Dale B, Elander R, Lee YY, Holtzapple M, Ladisch M, Bioresour. Technol., 96(6), 673 (2005)
- Danon B, van der Aa L, de Jong W, Carbohyd. Res., 375, 145 (2013)
- Rong C, Ding X, Zhu Y, Li Y, Wang L, Qu Y, Ma X, Wang Z, Carbohydr. Res., 350, 77 (2012)