Pb(Ni 1/3 Nb 2/3 )O 3 -PZT 세라믹스 고용체에서 과잉 NiO첨가에 따른 압전특성 변화

최용길; 손영진; 권준철; 조경원; 윤만순; 김일호; 김영민; 어순철; Y.G. Choi; Y.J. Son; J.C. Kweon; K.W. Cho; M.S. Yoon; I.H. Kim; Y.M. Kim; S.C. Ur

Korean Journal of Materials Research, Vol.15, No.6, 413-418, June, 2005

DOI10.3740/MRSK.2005.15.6.413 Export Citation

Pb(Ni 1/3 Nb 2/3 )O 3 -PZT 세라믹스 고용체에서 과잉 NiO첨가에 따른 압전특성 변화

The Effect of NiO Addition to the PNN-PZT Piezoelectric Ceramics on Piezoelectric Properties

최용길, 손영진, 권준철, 조경원, 윤만순, 김일호 , 김영민¹, 어순철 ^†

충주대학교 신소재공학과/친환경 에너지 변환 저장소재 및 부품개발 연구센터
¹고려전자(주) 소재개발부

Y.G. Choi, Y.J. Son, J.C. Kweon, K.W. Cho, M.S. Yoon, I.H. Kim , Y.M. Kim¹, and S.C. Ur^†

Department of Materials Science and Engineering/Research Center for Sustainble ECo-Devices and Materials (ReSEM), Chungju National University, Korea
¹Corea Electronics Corporation(CEC), Korea

E-mail:

Perovskite Pb(Ni 1/3 Nb 2/3 )O 3 ?Pb(Zr,Ti)O 3 [PNN?PZT] ceramics were synthesized by conventional ceramic processing technique. In order to modify piezoelectric properties for sensor application in this system, NiO addition was considered to provide Ni +2 as an acceptor, which was known to occupy with B site in the structure. The effect of NiO addition up to 8mol% on the following piezoelectric properties as well as sintering properties was investigated. When NiO added more than 1mol% , average grain size was decreased and second phase was found to form. Moreover, the second phase caused decrease in relative dielectric constant (ε 33 T/ε0) , electro-mechanical coupling factor (k p ) , and piezoelectric charge constant (d 33 ) , while increasing mechanical quality factor (Q m ) . When 1mol% NiO was added, density, dielectric properties and piezoelectric properties were abruptly increased.

Keywords:PNN-PZT;piezoelectric;NiO doping

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[1] Lebrun L, Guiffard B, Audigier D, Boucher E, Guyomar D, Eyraud L, Pleska E, J. European Ceram. Soc., 21, 1357 (2001)

[2] Pferner RA, Thurn G, Aldinger F, Mater. Chem. Phys., 61, 24 (1999)

[3] Rukmini HR, Choudhary RNP, Rao VV, Mater. Chem. Phys., 55, 108 (1998)

[4] Barranco AP, Pinar FC, Mattinez P, Garciaet ET, J. Euro. Ceram. Soc., 21, 523 (2001)

[5] Berlincourt D, 'Parameters of Piezoelectric Ceramics, in Ultrasonic Transducer Materials 100', Mattiat OE, Plenum Press, Newyork-London (1971) (1971)

[6] Fukumoto A, Ferroelectrics, 40, 217 (1982)

[7] Nguyen HV, Srinivasan TT, Newnham RE, Bhalla AS, 'Hysteretic Forces on a Magnet Levitation above the high Tc Superconductor / Polymer 0-3 composite,' 112-SVI-89, 91th Annual of American Ceramic Soc. Indianapolis, Indiana, USA (1989) (1989)

[8] Zhong WL, Wang YG, Yue SB, Zhang PL, Soild State Comm., 90(6), 383 (1994)

[9] Chu SY, Chen TY, Tsai IT, Mater. Lett., 53, 752 (2004)

[10] Takahashi S, Hirose S, Jpn. J. Appl. Phys., 31(9B), 3055 (1992)

[11] Takenaka T, Bhalla AS, Cross LE, J. Am. Ceram. Soc., 72(6), 1016 (1989)

[12] Ikeda T, 'Fundamentals of Piezoelectricity', Tohoku., Japan, 221 (1980) (1980)

[13] Gui Z, Li L, Lin H, Zhang X, Ferroelectric, 101, 93 (1990)

[14] Kanegae T, Sakada K, Takenak T, Jpn. J. Appl. Phys., 30(9B), 2232 (1991)

[15] Khim AS, Wang J, Junmin X, J. Alloys Comp., 311(2), 181 (2000)

[16] Wang J, Wan DM, Xue JM, Ng WB, Am. Ceram. Soc., 82, 477 (1999)

[17] IRE Standards on Piezoelectric Crystals: Measurements of piezoelectric ceramics, Proc. IRE, 49, 1161 (1961) (1961)

[18] Swartz SL, Shrout TR, Mater. Res. Bull., 1245 (1982)

[19] Kakegawa K, Mohri J, Shirasaki S, Takahashi K, J. Am. Ceram. Soc., 65, 515 (1982)

[20] Wurst JC, Nelson JA, J. Am. Cerm, Soc., 55, 450 (1972)

[21] Na ES, Kim YH, Choi SC, Journal of the Korean Association of Crystal Growth., 10(2), 245 (2000)

[22] Jaffe B, Piezoelectric Ceramics, Academic Press., 33, (1971) (1971)

[23] Okazaki K, Nagata K, J. Am. Cerm. Soc., 56(2), 82 (1973)

[24] Kamiya T, Susuki T, Turumi T, Jpn. J. Appl. Phys., 31(9B), 3058 (1992)

[25] Robels U, Schneider-Stotmann L, Arlt G, Ferroelectrics., 133, 223 (1992)